For nearly a century, the Fischer–Tropsch (FT) reaction has been subject of intense debate.
Various molecular views on the active sites and on the reaction mechanism have been …

The design of heterogeneous catalysts relies on understanding the fundamental surface
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …

Hydrogen is currently mainly produced via steam reforming of methane (SMR: CH4+ H2O→
CO+ 3H2). An alternative to this process, utilizing carbon dioxide and thus potentially …

Under specific scenarios, the catalytic hydrogenation of CO2 with renewable hydrogen is
considered a suitable route for the chemical recycling of this environmentally harmful and …

Catalytic routes for upgrading CO2 to CO and hydrocarbons have been studied for decades,
and yet the mechanistic details and structure–function relationships that control catalytic …

Fischer-Tropsch (FT) process has great potential to accomplish energy security but also for
utilizing greenhouse gases to address the energy problem. Different kinds of feedstocks like …

Microkinetic analysis plays an important role in catalyst design because it provides insight
into the fundamental surface chemistry that controls catalyst performance. In this review, we …

Enrique Iglesia is an internationally recognized leader in the field of heterogeneous
catalysis. His trademark approach places a premium on kinetic and mechanistic descriptions …

The effect of H2 partial pressure in a wide range (P H2= 0.12–0.6 bar, or H2/CO gas ratio of
2–10; P CO= 0.06 bar) on important kinetic parameters of the methanation reaction at 230° …

Understanding the dynamic changes at the active site during catalysis is a fundamental
challenge that promises to improve catalytic properties. While performing Arrhenius studies …