Recent developments in penta-, hexa-and heptadentate Schiff base ligands and their metal complexes
X Liu, JR Hamon - Coordination Chemistry Reviews, 2019 - Elsevier
Novel ligand platforms that promote reactivity are of long standing and continued interest in
coordination chemistry, with Schiff base ligands and their metal complexes representing one …
coordination chemistry, with Schiff base ligands and their metal complexes representing one …
Spin crossover in iron (III) complexes
Spin crossover compounds are a diverse class of switchable materials with applications
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
Solvent modified spin crossover in an iron (III) complex: phase changes and an exceptionally wide hysteresis
Solvent effects in a series of Fe (III) spin crossover (SCO) complexes [Fe (qsal-I) 2] OTf· sol
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
(sol= MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is …
Thermal spin crossover in Fe (II) and Fe (III). Accurate spin state energetics at the solid state
The thermal spin crossover (SCO) phenomenon refers to an entropy-driven spin transition in
some materials based on d6–d9 transition metal complexes. While its molecular origin is …
some materials based on d6–d9 transition metal complexes. While its molecular origin is …
The molecular and supramolecular aspects in mononuclear manganese (III) Schiff-base spin crossover complexes
S Wang, YJ Li, FF Ju, WT Xu, K Kagesawa, YH Li… - Dalton …, 2017 - pubs.rsc.org
Manganese (III) hexadentate Schiff base complexes ([Mn (sal-N-1, 5, 8, 12)] Y· S, Y= AsF6
(1); Y= SbF6 (2); Y= NO3, S= C2H5OH (3) and Y= Cl (4)) have been investigated to …
(1); Y= SbF6 (2); Y= NO3, S= C2H5OH (3) and Y= Cl (4)) have been investigated to …
Recent advances on iron-based photoinitiators of polymerization
F Dumur - European Polymer Journal, 2020 - Elsevier
With regards to the environmental and safety concerns raised nowadays by the polymer
industry, polymerization processes requiring light as the activation source are currently …
industry, polymerization processes requiring light as the activation source are currently …
Spin-crossover in an iron (iii) complex showing a broad thermal hysteresis
C Rajnák, R Mičová, J Moncoľ, Ľ Dlháň, C Krüger… - Dalton …, 2021 - pubs.rsc.org
A pentadentate Schiff-base ligand 3, 5Cl-L2− and NCSe− form an iron (III) mononuclear
complex, namely [Fe (3, 5Cl-L)(NCSe)], which shows a thermally induced spin crossover …
complex, namely [Fe (3, 5Cl-L)(NCSe)], which shows a thermally induced spin crossover …
Structural insights into the counterion effects on the manganese (III) spin crossover system with hexadentate Schiff-base ligands
A series of new salts [Mn (5-MeO-sal-N-1, 5, 8, 12)] Y (Y= ClO4 for 1, Y= BF4 for 2, Y= NO3
for 3 and Y= CF3SO3 for 4) based on the six-coordinated mononuclear manganese (III) …
for 3 and Y= CF3SO3 for 4) based on the six-coordinated mononuclear manganese (III) …
Above room temperature spin transition in thermally stable mononuclear Fe (III) complexes
Two solvent-free mononuclear Fe (III) complexes [Fe (L) 2] NO3 (1) and [Fe (L) 2] ClO4 (2)
have been synthesized by employing a new π-conjugated azo-phenyl substituted ligand, 2 …
have been synthesized by employing a new π-conjugated azo-phenyl substituted ligand, 2 …
Spin crossover in 3D metal centers binding halide-containing ligands: Magnetism, structure and computational studies
The capability of a given substance to change its spin state by the action of a stimulus, such
as a change in temperature, is by itself a very challenging property. Its interest is increased …
as a change in temperature, is by itself a very challenging property. Its interest is increased …