The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Lanthanide (Ln) compounds represent a unique chemical platform for develo** high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …

The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …

Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …

Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …