Late-metal catalysts for ethylene homo-and copolymerization

SD Ittel, LK Johnson, M Brookhart - Chemical Reviews, 2000 - ACS Publications
Polyolefins are a multibillion dollar a year industry with worldwide production in excess of
160 billion pounds and polyethylene alone in excess of 100 billion pounds. Despite this size …

Coordination− insertion copolymerization of fundamental polar monomers

A Nakamura, S Ito, K Nozaki - Chemical reviews, 2009 - ACS Publications
Akifumi Nakamura (left) was born in 1984 in Kanagawa, Japan. He received his BS degree
in 2007 and MS degree in 2009 from the University of Tokyo under the guidance of …

Chemically recyclable polyolefin-like multiblock polymers

Y Zhao, EM Rettner, KL Harry, Z Hu, J Miscall… - Science, 2023 - science.org
Polyolefins are the most important and largest volume plastics produced. Unfortunately, the
enormous use of plastics and lack of effective disposal or recycling options have created a …

Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism

BC Vance, PA Kots, C Wang, JE Granite… - Applied Catalysis B …, 2023 - Elsevier
Noble metal-based hydrogenolysis is emerging as a key chemical deconstruction
technology of polyolefins into valuable products. Still, the catalyst cost and availability are …

A reusable, impurity-tolerant and noble metal–free catalyst for hydrocracking of waste polyolefins

Z Qiu, S Lin, Z Chen, A Chen, Y Zhou, X Cao… - Science …, 2023 - science.org
One-step conversion of low-purity polyolefins to value-added products without pretreatments
represents a great opportunity for chemical recycling of waste plastics. However, additives …

Synthesis of branched polyethylene using (α-diimine) nickel (II) catalysts: influence of temperature, ethylene pressure, and ligand structure on polymer properties

DP Gates, SA Svejda, E Oñate, CM Killian… - …, 2000 - ACS Publications
Detailed investigations of the polymerization of ethylene by (α-diimine) nickel (II) catalysts
are reported. Effects of structural variations of the diimine ligand on catalyst activities …

Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations1

DJ Tempel, LK Johnson, RL Huff… - Journal of the …, 2000 - ACS Publications
Mechanistic studies of olefin polymerizations catalyzed by aryl-substituted α-diimine− Pd (II)
complexes are presented. Syntheses of several cationic catalyst precursors,[(N∧ N) Pd …

Depolymerization of waste plastics to monomers and chemicals using a hydrosilylation strategy facilitated by Brookhart's iridium (III) catalyst

L Monsigny, JC Berthet, T Cantat - ACS Sustainable Chemistry & …, 2018 - ACS Publications
Plastic waste management is a major concern. While the societal demand for sustainability
is growing, landfilling and incineration of waste plastics remain the norm and methods able …

Extrusion polymerization: catalyzed synthesis of crystalline linear polyethylene nanofibers within a mesoporous silica

K Kageyama, J Tamazawa, T Aida - Science, 1999 - science.org
Crystalline nanofibers of linear polyethylene with an ultrahigh molecular weight (6,200,000)
and a diameter of 30 to 50 nanometers were formed by the polymerization of ethylene with …

Single-site heterogeneous catalysts for olefin polymerization enabled by cation exchange in a metal-organic framework

RJ Comito, KJ Fritzsching, BJ Sundell… - Journal of the …, 2016 - ACS Publications
The manufacture of advanced polyolefins has been critically enabled by the development of
single-site heterogeneous catalysts. Metal-organic frameworks (MOFs) show great potential …