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Reduced transition metal colloids: a novel family of reusable catalysts?
A Roucoux, J Schulz, H Patin - Chemical reviews, 2002 - ACS Publications
The word “colloid” was introduced for the first time by Graham in 18611 to describe the very
slow sedimentation and noncrystalline state, two characteristic appearances of aqueous …
slow sedimentation and noncrystalline state, two characteristic appearances of aqueous …
A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
JA Widegren, RG Finke - Journal of Molecular Catalysis A: Chemical, 2003 - Elsevier
This review considers cases in which a discrete transition-metal complex is used as a
precatalyst for reductive catalysis; it focuses on the problem of determining if the true catalyst …
precatalyst for reductive catalysis; it focuses on the problem of determining if the true catalyst …
A review of soluble transition-metal nanoclusters as arene hydrogenation catalysts
JA Widegren, RG Finke - Journal of Molecular Catalysis A: Chemical, 2003 - Elsevier
A critical review of the use of soluble transition-metal nanoclusters for the hydrogenation of
monocyclic aromatic compounds is presented. The review begins with a brief introduction to …
monocyclic aromatic compounds is presented. The review begins with a brief introduction to …
Is it homogeneous or heterogeneous catalysis? Identification of bulk ruthenium metal as the true catalyst in benzene hydrogenations starting with the monometallic …
JA Widegren, MA Bennett, RG Finke - Journal of the American …, 2003 - ACS Publications
A reinvestigation of the true catalyst in a benzene hydrogenation system beginning with Ru
(II)(η6-C6Me6)(OAc) 2 as the precatalyst is reported. The key observations leading to the …
(II)(η6-C6Me6)(OAc) 2 as the precatalyst is reported. The key observations leading to the …
Arene hydrogenation in a room-temperature ionic liquid using a ruthenium cluster catalyst
The air and moisture stable system [bmim][BF4]–[Ru4 (η6-C6H6) 4][BF4]{[bmim]+= 1-butyl-3-
methylimidazolium cation} presents a novel medium for conducting hydrogenations of …
methylimidazolium cation} presents a novel medium for conducting hydrogenations of …
Arene hydrogenation by homogeneous catalysts: fact or fiction?
PJ Dyson - Dalton Transactions, 2003 - pubs.rsc.org
A few years ago the concept of homogeneous arene hydrogenation catalysis was called into
question, since many catalysts originally assigned as homogeneous have subsequently …
question, since many catalysts originally assigned as homogeneous have subsequently …
A Convenient Synthetic Route to [CpRu(CH3CN)3]PF6
BM Trost, CM Older - Organometallics, 2002 - ACS Publications
A Convenient Synthetic Route to [CpRu(CH3CN)3]PF6 | Organometallics Recently Viewed
close modal ACS ACS Publications C&EN CAS Find my institution Log In ACS Publications …
close modal ACS ACS Publications C&EN CAS Find my institution Log In ACS Publications …
[KIRJA][B] New pathways for organic synthesis: practical applications of transition metals
HM Colquhoun, J Holton, DJ Thompson, MV Twigg - 2012 - books.google.com
The continually growing contribution of transition metal chemistry to synthetic organic
chemistry is, of course, widely recognized. Equally well known is the difficulty in kee** up …
chemistry is, of course, widely recognized. Equally well known is the difficulty in kee** up …
Hydrogenation of arenes under mild conditions using rhodium pyridylphosphine and bipyridyl complexes tethered to a silica-supported palladium heterogeneous …
H Yang, H Gao, RJ Angelici - Organometallics, 2000 - ACS Publications
The rhodium complexes [Rh (COD)(1)] BF4 (Rh (N− P)) and [Rh (COD)(2)] BF4 (Rh (N− N)),
containing the new pyridylphosphine and bipyridyl ligands (1 and 2) with alkoxysilane …
containing the new pyridylphosphine and bipyridyl ligands (1 and 2) with alkoxysilane …
Developments in the chemistry of tris (hydroxymethyl) phosphine
BR James, F Lorenzini - Coordination Chemistry Reviews, 2010 - Elsevier
Tris (hydroxymethyl) phosphine, P (CH2OH) 3, a water-soluble compound, has been known
for about 50 years but development of its coordination chemistry has been slow and …
for about 50 years but development of its coordination chemistry has been slow and …