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Reaction dynamics studied via femtosecond X-ray liquidography at X-ray free-electron lasers
X-ray free-electron lasers (XFELs) provide femtosecond X-ray pulses suitable for pump–
probe time-resolved studies with a femtosecond time resolution. Since the advent of the first …
probe time-resolved studies with a femtosecond time resolution. Since the advent of the first …
[HTML][HTML] Structural dynamics of proteins explored via time-resolved x-ray liquidography
The structure of a protein is closely related to its biological function. In this regard, structural
changes, as well as static structures, have been scrutinized as essential elements in …
changes, as well as static structures, have been scrutinized as essential elements in …
Filming ultrafast roaming-mediated isomerization of bismuth triiodide in solution
Roaming reaction, defined as a reaction yielding products via reorientational motion in the
long-range region (3–8 Å) of the potential, is a relatively recently proposed reaction pathway …
long-range region (3–8 Å) of the potential, is a relatively recently proposed reaction pathway …
[HTML][HTML] Projection to extract the perpendicular component (PEPC) method for extracting kinetics from time-resolved data
Time-resolved x-ray liquidography (TRXL) is a potent method for investigating the structural
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
The carbon–iodine bond cleavage and isomerization of iodoform visualized with femtosecond X-ray liquidography
Iodoform (CHI3) has garnered significant attention for its unique ability to induce photo-
cyclopropanation of olefins by releasing an iodine radical through C–I bond cleavage …
cyclopropanation of olefins by releasing an iodine radical through C–I bond cleavage …
Structural dynamics of bismuth triiodide in solution triggered by photoinduced ligand-to-metal charge transfer
EH Choi, DS Ahn, S Park, C Kim, CW Ahn… - The Journal of …, 2019 - ACS Publications
Bismuth triiodide, BiI3, is one of the simplest bismuth halides, which have recently attracted
considerable attention because of their promising properties. Here, we investigate the …
considerable attention because of their promising properties. Here, we investigate the …
Femtosecond x-ray liquidography visualizes wavepacket trajectories in multidimensional nuclear coordinates for a bimolecular reaction
Conspectus Vibrational wavepacket motions on potential energy surfaces are one of the
critical factors that determine the reaction dynamics of photoinduced reactions. The motions …
critical factors that determine the reaction dynamics of photoinduced reactions. The motions …
Extracting kinetics and thermodynamics of molecules without heavy atoms via time-resolved solvent scattering signals
KY Oang, S Park, J Moon, E Park, HK Lee… - The Journal of …, 2023 - ACS Publications
Time-resolved X-ray liquidography (TRXL) has emerged as a powerful technique for
studying the structural dynamics of small molecules and macromolecules in liquid solutions …
studying the structural dynamics of small molecules and macromolecules in liquid solutions …
Sensitivity of time‐resolved diffraction data to changes in internuclear distances and atomic positions
Time‐resolved x‐ray liquidography (TRXL) is a powerful technique to study molecular
structural dynamics in the solution phase. Typically, a TRXL experiment is conducted during …
structural dynamics in the solution phase. Typically, a TRXL experiment is conducted during …
[HTML][HTML] Solvent-dependent complex reaction pathways of bromoform revealed by time-resolved X-ray solution scattering and X-ray transient absorption spectroscopy
The photochemical reaction pathways of CHBr 3 in solution were unveiled using two
complementary X-ray techniques, time-resolved X-ray solution scattering (TRXSS) and X-ray …
complementary X-ray techniques, time-resolved X-ray solution scattering (TRXSS) and X-ray …