Complexes featuring tridentate iminophosphorane ligands: Synthesis, reactivity, and catalysis
T Tannoux, A Auffrant - Coordination Chemistry Reviews, 2023 - Elsevier
Even if iminophosphoranes (R 3 P= NR′) were described more than a century ago they
remain much less investigated in coordination chemistry than phosphine or N-heterocyclic …
remain much less investigated in coordination chemistry than phosphine or N-heterocyclic …
Lanthanoid complexes as molecular materials: the redox approach
MA Hay, C Boskovic - Chemistry–A European Journal, 2021 - Wiley Online Library
The development of molecular materials with novel functionality offers promise for
technological innovation. Switchable molecules that incorporate redox‐active components …
technological innovation. Switchable molecules that incorporate redox‐active components …
Catalytic recycling of a Th–H bond via single or double hydroboration of inactivated imines or nitriles
The catalytic activity of the metallacycle thorium amide [(Me3Si) 2N] 2Th [κ2–(N, C)–CH2Si
(CH3) 2N (SiMe3)](Th1) is presented for the selective dihydroboration of nitriles (—C≡ N) …
(CH3) 2N (SiMe3)](Th1) is presented for the selective dihydroboration of nitriles (—C≡ N) …
Carbonyl group and carbon dioxide activation by rare-earth-metal complexes
U Bayer, R Anwander - Dalton Transactions, 2020 - pubs.rsc.org
The rare-earth elements (Ln= Sc, Y, La–Lu) are widely used in stoichiometric and catalytic
carbonyl group transformations. Sufficient availability, non-toxicity, high oxophilicity, tunable …
carbonyl group transformations. Sufficient availability, non-toxicity, high oxophilicity, tunable …
Mild catalytic deoxygenation of amides promoted by thorium metallocene
The organoactinide-catalyzed (Cp* 2ThMe2) hydroborated reduction of a wide range of
tertiary, secondary, and primary amides to the corresponding amines/amine–borane …
tertiary, secondary, and primary amides to the corresponding amines/amine–borane …
High-Frequency and -Field Electron Paramagnetic Resonance Spectroscopic Analysis of Metal–Ligand Covalency in a 4f7 Valence Series (Eu2+, Gd3+, and Tb4+)
The recent isolation of molecular tetravalent lanthanide complexes has enabled renewed
exploration of the effect of oxidation state on the single-ion properties of the lanthanide ions …
exploration of the effect of oxidation state on the single-ion properties of the lanthanide ions …
Electronic Effects in Phosphino‐Iminophosphorane PdII Complexes upon Varying the N Substituent
I Popovici, E Lognon, N Casaretto… - … A European Journal, 2024 - Wiley Online Library
Three series of palladium (II) complexes supported by a phosphine‐iminophosphorane
ligand built upon an ortho‐phenylene core were investigated to study the influence of the …
ligand built upon an ortho‐phenylene core were investigated to study the influence of the …
Inverse coordination. Organic nitrogen heterocycles as coordination centers. A survey of molecular topologies and systematization. Part 2. Six-membered rings
I Haiduc - Journal of Coordination Chemistry, 2019 - Taylor & Francis
The review is a follow-up of a previous article (I. Haiduc, J. Coord. Chem.(2019). DOI:
10.1080/00958972.2019. 1641702), which introduced structures with five-membered …
10.1080/00958972.2019. 1641702), which introduced structures with five-membered …
Tridentate NNN ligand associating amidoquinoline and iminophosphorane: synthesis and coordination to Pd and Ni centers
L Mazaud, M Tricoire, S Bourcier, M Cordier… - …, 2020 - ACS Publications
The synthesis of a tridentate NNN ligand incorporating an amidoquinoline and an
iminophosphorane (LRH; R= Ph, Cy) was carried out. Coordination to PdII and NiII …
iminophosphorane (LRH; R= Ph, Cy) was carried out. Coordination to PdII and NiII …
Phosphazenes
V Chandrasekhar, RS Narayanan - 2017 - books.rsc.org
Phosphazenes are compounds that contain a formal P¼N unit. Various types of
phosphazenes are continuously being investigated for many reasons, including synthesis …
phosphazenes are continuously being investigated for many reasons, including synthesis …