Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS)

K Tanaka, Y Chujo - Journal of Materials Chemistry, 2012 - pubs.rsc.org
Polysilsesquioxanes are regarded as organic–inorganic hybrid materials at a molecular
level. We can readily tune the properties of the materials for realizing the desired ones by …

Bioconjugation on cube-octameric silsesquioxanes

S Fabritz, S Hörner, O Avrutina… - Organic & biomolecular …, 2013 - pubs.rsc.org
Small, compact, and highly symmetric cube-octameric silsesquioxanes have recently
attracted increased attention as scaffolds for tailor-made bioconjugates. The expanded …

Anion identification using silsesquioxane cages

S Chanmungkalakul, V Ervithayasuporn… - Chemical …, 2018 - pubs.rsc.org
Anthracene-conjugated octameric silsesquioxane (AnSQ) cages, prepared via Heck
coupling between octavinylsilsesquioxane (OVS) and 9-bromoanthracene …

Synthesis and Isolation of Methacrylate- and Acrylate-Functionalized Polyhedral Oligomeric Silsesquioxanes (T8, T10, and T12) and Characterization of the …

V Ervithayasuporn, S Chimjarn - Inorganic Chemistry, 2013 - ACS Publications
Novel organic–inorganic hybrid nanobuilding blocks of methacrylate-and acrylate-
functionalized polyhedral oligomeric silsesquioxanes were easily prepared via nucleophilic …

Synthesis of a novel organic-inorganic hindered phenol antioxidant derived from polyhedral oligomeric silsesquioxane and its anti-oxidative behavior in …

J Zhang, Q Ke, J Bai, M Yang - Polymer Degradation and Stability, 2023 - Elsevier
To explore antioxidants with high anti-aging efficiency and admirable anti-extraction ability,
a novel organic-inorganic hindered phenol antioxidant (AO-POSS) derived from polyhedral …

Synthesis of aromatic functionalized cage-rearranged silsesquioxanes (T 8, T 10, and T 12) via nucleophilic substitution reactions

S Chimjarn, R Kunthom, P Chancharone… - Dalton …, 2015 - pubs.rsc.org
Organic–inorganic hybrid nano-building blocks of aromatic nitro-, aldehyde-, and bromo-
functionalized polyhedral oligomeric silsesquioxanes were easily prepared through …

Synthesis of poly (siloxane/double-decker silsesquioxane) via dehydrocarbonative condensation reaction and its functionalization

R Sodkhomkhum, V Ervithayasuporn - Polymer, 2016 - Elsevier
Chlorine-containing poly (siloxane/double-decker silsesquioxane)(P–Cl) was prepared in
high yield at ambient room temperature via dehydrocarbonative polycondensation reaction …

Assembly of Coordination Polymers Using Thioether‐Functionalized Octasilsesquioxanes: Occurrence of (CuX)n Clusters (X=Br and I) within 3D‐POSS Networks

A Raghuvanshi, C Strohmann, JB Tissot… - … A European Journal, 2017 - Wiley Online Library
For the first time, POSS‐based coordination polymers (CPs) have been structurally
characterized. These CPs were obtained in high yield via self‐assembly reactions of …

Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores

Y Liu, M Kigure, R Okawa, N Takeda, M Unno… - Dalton …, 2021 - pubs.rsc.org
Tetra (3-mercaptopropyl)-silsesquioxanes with double-decker (DDSQ) or ladder nano-cores
were easily prepared from the corresponding tetraallyl derivatives through fast and …

Synthesis and reactivity of nitrogen nucleophiles-induced cage-rearrangement silsesquioxanes

T Jaroentomeechai, P Yingsukkamol, C Phurat… - Inorganic …, 2012 - ACS Publications
Novel phthalimide and o-sulfobenzimide-functionalized silsesquioxanes were successfully
synthesized via nucleophilic substitution reactions from octakis (3-chloropropyl) …