Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Transition-metal-catalyzed reductive coupling reactions have been considered as a
powerful tool to convert two electrophiles into value-added products. Numerous related …

Grignard addition is one of the most important methods used for syntheses of alcohol
compounds and has been known for over a hundred years. However, research on …

Asymmetric reductive three-component arylalkylation of alkenes via the radical relay method
has been well established, while asymmetric arylalkylation via the migratory insertion …

A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …

The catalytic cross-coupling of identical or similar functional groups is a cornerstone strategy
for carbon–carbon bond formation, as exemplified by renowned methods, such as olefin …

The ability to tame high-energy intermediates is important for synthetic chemistry, enabling
the construction of complex molecules and propelling advances in the field of synthesis …

A simple and general method for anti-selective hydrosulfonylation of unactivated alkynes
with sulfonyl chlorides in the presence of a catalytic amount of phenanthroline-based Lewis …

Internal alkynes are widespread skeletons in bioactive molecules and materials which are
also used as important building blocks in chemical synthesis. Herein, we report a novel and …

This research explores the enantioselective hydrosulfonylation of various α, β‐unsaturated
carbonyl compounds via the use of visible light and redox‐active chiral Ni‐catalysis …