Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Mobility of nonsticky nanoparticles in polymer liquids

LH Cai, S Panyukov, M Rubinstein - Macromolecules, 2011 - ACS Publications
We use scaling theory to derive the time dependence of the mean-square displacement⟨ Δ r
2⟩ of a probe nanoparticle of size d experiencing thermal motion in polymer solutions and …

Hop** diffusion of nanoparticles in polymer matrices

LH Cai, S Panyukov, M Rubinstein - Macromolecules, 2015 - ACS Publications
We propose a hop** mechanism for diffusion of large nonsticky nanoparticles subjected to
topological constraints in both unentangled and entangled polymer solids (networks and …

Phase stability and dynamics of entangled polymer–nanoparticle composites

R Mangal, S Srivastava, LA Archer - Nature communications, 2015 - nature.com
Nanoparticle–polymer composites, or polymer–nanoparticle composites (PNCs), exhibit
unusual mechanical and dynamical features when the particle size approaches the random …

Particle tracking of nanoparticles in soft matter

KA Rose, M Molaei, MJ Boyle, D Lee… - Journal of Applied …, 2020 - pubs.aip.org
Recent advances in optical microscopy instrumentation and processing techniques have led
to imaging that both breaks the diffraction barrier and enables sub-pixel resolution. This …

Nanoparticle diffusion in polymer nanocomposites

JT Kalathi, U Yamamoto, KS Schweizer, GS Grest… - Physical review …, 2014 - APS
Large-scale molecular dynamics simulations show that nanoparticle (NP) diffusivity in
weakly interacting mixtures of NPs and polymer melts has two very different classes of …

Macromolecule and particle dynamics in confined media

CC Lin, E Parrish, RJ Composto - Macromolecules, 2016 - ACS Publications
Dynamic properties play an important role in designing functional polymer nanocomposites,
impacting molecular transport and phase separation kinetics. When nanoparticle (NP) size …

Influence of the bound polymer layer on nanoparticle diffusion in polymer melts

PJ Griffin, V Bocharova, LR Middleton… - ACS Macro …, 2016 - ACS Publications
We measure the center-of-mass diffusion of silica nanoparticles (NPs) in entangled poly (2-
vinylpyridine)(P2VP) melts using Rutherford backscattering spectrometry. While these NPs …

Theory of nanoparticle diffusion in unentangled and entangled polymer melts

U Yamamoto, KS Schweizer - The Journal of chemical physics, 2011 - pubs.aip.org
We propose a statistical dynamical theory for the violation of the hydrodynamic Stokes-
Einstein (SE) diffusion law for a spherical nanoparticle in entangled and unentangled …

Size effect of nanoparticle diffusion in a polymer melt

CA Grabowski, A Mukhopadhyay - Macromolecules, 2014 - ACS Publications
We investigated the dynamics of gold nanoparticles (NPs) within an entangled liquid of poly
(n-butyl methacrylate)(PBMA) above the glass transition temperature (T g). The experiments …