Recent developments in entropy‐driven ring‐opening metathesis polymerization: Mechanistic considerations, unique functionality, and sequence control
ABSTRACT Entropy‐driven ROMP (ED‐ROMP) involves polymerization of olefin‐containing
macrocyclic monomers under entropically favorable conditions. Macrocycles can be …
macrocyclic monomers under entropically favorable conditions. Macrocycles can be …
A precise polyrotaxane synthesizer
Mechanically interlocked molecules are likely candidates for the design and synthesis of
artificial molecular machines. Although polyrotaxanes have already found niche applications …
artificial molecular machines. Although polyrotaxanes have already found niche applications …
Olefin metathesis reaction as a locking tool for macrocycle and mechanomolecule construction
The present review deals with an updated visit to the olefin metathesis reaction as a
powerful tool for the construction of sophisticated macromolecular architectures. Today, the …
powerful tool for the construction of sophisticated macromolecular architectures. Today, the …
Woven polymer networks via the topological transformation of a [2] catenane
Weaving technology has been widely used to manufacture macroscopic fabrics to meet the
artistic and practical needs of humanity for thousands of years. However, the fabrication of …
artistic and practical needs of humanity for thousands of years. However, the fabrication of …
Iterative Synthesis of Oligo[n]rotaxanes in Excellent Yield
JEM Lewis, J Winn, L Cera… - Journal of the American …, 2016 - ACS Publications
We present an operationally simple iterative coupling strategy for the synthesis of oligomeric
homo-and hetero [n] rotaxanes with precise control over the position of each macrocycle …
homo-and hetero [n] rotaxanes with precise control over the position of each macrocycle …
A multi-stimuli responsive metallosupramolecular polypseudorotaxane gel constructed by self-assembly of a pillar [5] arene-based pseudo [3] rotaxane via zinc ion …
JD Ding, JF Chen, Q Lin, H Yao, YM Zhang… - Polymer Chemistry, 2018 - pubs.rsc.org
A novel metallosupramolecular polypseudorotaxane has been successfully prepared via a
pillar [5] arene-based pseudo [3] rotaxane and zinc ion coordination. The obtained …
pillar [5] arene-based pseudo [3] rotaxane and zinc ion coordination. The obtained …
Ring-opening metathesis polymerization of a diolefinic [2]-catenane–copper (I) complex: an easy route to polycatenanes
A dilute (30 mM) dichloromethane solution of the copper (I) complex 1· Cu+ of a [2]-catenane
composed of two identical 28-membered macrocyclic alkenes featuring a phenanthroline …
composed of two identical 28-membered macrocyclic alkenes featuring a phenanthroline …
Characterization and photocatalytic behavior of 2, 9-di (aryl)-1, 10-phenanthroline copper (I) complexes
The synthesis, characterization, photophysical properties, theoretical calculations, and
catalytic applications of 2, 9-di (aryl)-1, 10-phenanthroline copper (I) complexes are …
catalytic applications of 2, 9-di (aryl)-1, 10-phenanthroline copper (I) complexes are …
Insights into the Difference between Rotaxane and Pseudorotaxane
HL Sun, HY Zhang, Z Dai, X Han… - Chemistry–An Asian …, 2017 - Wiley Online Library
Rotaxane and pseudorotaxane are two types of mechanically interlocked molecular
architectures, and there is a clear topological difference and boundary between them. In this …
architectures, and there is a clear topological difference and boundary between them. In this …
Nanoporous phenanthroline polymer locked Pd as highly efficient catalyst for Suzuki‐Miyaura Coupling reaction at room temperature
J Chen, J Zhang, Y Zhang, M ** a high‐performance …