Extended tight‐binding quantum chemistry methods

C Bannwarth, E Caldeweyher, S Ehlert… - Wiley …, 2021 - Wiley Online Library
This review covers a family of atomistic, mostly quantum chemistry (QC) based
semiempirical methods for the fast and reasonably accurate description of large molecules …

Computational discovery of transition-metal complexes: from high-throughput screening to machine learning

A Nandy, C Duan, MG Taylor, F Liu, AH Steeves… - Chemical …, 2021 - ACS Publications
Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

[HTML][HTML] The ORCA quantum chemistry program package

F Neese, F Wennmohs, U Becker… - The Journal of chemical …, 2020 - pubs.aip.org
In this contribution to the special software-centered issue, the ORCA program package is
described. We start with a short historical perspective of how the project began and go on to …

Stability-limiting heterointerfaces of perovskite photovoltaics

S Tan, T Huang, I Yavuz, R Wang, TW Yoon, M Xu… - Nature, 2022 - nature.com
Optoelectronic devices consist of heterointerfaces formed between dissimilar
semiconducting materials. The relative energy-level alignment between contacting …

Mol* Viewer: modern web app for 3D visualization and analysis of large biomolecular structures

D Sehnal, S Bittrich, M Deshpande… - Nucleic acids …, 2021 - academic.oup.com
Large biomolecular structures are being determined experimentally on a daily basis using
established techniques such as crystallography and electron microscopy. In addition …

GFN2-xTB—An accurate and broadly parametrized self-consistent tight-binding quantum chemical method with multipole electrostatics and density-dependent …

C Bannwarth, S Ehlert, S Grimme - Journal of chemical theory and …, 2019 - ACS Publications
An extended semiempirical tight-binding model is presented, which is primarily designed for
the fast calculation of structures and noncovalent interaction energies for molecular systems …

Automated exploration of the low-energy chemical space with fast quantum chemical methods

P Pracht, F Bohle, S Grimme - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
We propose and discuss an efficient scheme for the in silico sampling for parts of the
molecular chemical space by semiempirical tight-binding methods combined with a meta …

[HTML][HTML] DFTB+, a software package for efficient approximate density functional theory based atomistic simulations

B Hourahine, B Aradi, V Blum, F Bonafe… - The Journal of …, 2020 - pubs.aip.org
DFTB+ is a versatile community developed open source software package offering fast and
efficient methods for carrying out atomistic quantum mechanical simulations. By …

Exploration of chemical compound, conformer, and reaction space with meta-dynamics simulations based on tight-binding quantum chemical calculations

S Grimme - Journal of chemical theory and computation, 2019 - ACS Publications
The semiempirical tight-binding based quantum chemistry method GFN2-xTB is used in the
framework of meta-dynamics (MTD) to globally explore chemical compound, conformer, and …

A look at the density functional theory zoo with the advanced GMTKN55 database for general main group thermochemistry, kinetics and noncovalent interactions

L Goerigk, A Hansen, C Bauer, S Ehrlich… - Physical Chemistry …, 2017 - pubs.rsc.org
We present the GMTKN55 benchmark database for general main group thermochemistry,
kinetics and noncovalent interactions. Compared to its popular predecessor GMTKN30 …