Towards chemistry at absolute zero
BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …
intriguing questions about how chemical reactivity changes under these extreme conditions …
Molecular excitation in the interstellar medium: Recent advances in collisional, radiative, and chemical processes
E Roueff, F Lique - Chemical reviews, 2013 - ACS Publications
Our main knowledge about astrophysical environments relies on radiative spectra.
Absorption studies require background sources that are located hapharzadly in …
Absorption studies require background sources that are located hapharzadly in …
Perspective: Ultracold molecules and the dawn of cold controlled chemistry
N Balakrishnan - The Journal of chemical physics, 2016 - pubs.aip.org
Ultracold molecules offer unprecedented opportunities for the controlled interrogation of
molecular events, including chemical reactivity in the ultimate quantum regime. The …
molecular events, including chemical reactivity in the ultimate quantum regime. The …
Observation of resonances in Penning ionization reactions at sub-kelvin temperatures in merged beams
Experiments have lagged theory in exploring chemical interactions at temperatures so low
that translational degrees of freedom can no longer be treated classically. The difficulty has …
that translational degrees of freedom can no longer be treated classically. The difficulty has …
Imaging the onset of the resonance regime in low-energy NO-He collisions
At low energies, the quantum wave–like nature of molecular interactions results in distinctive
scattering behavior, ranging from the universal Wigner laws near 0 kelvin to the occurrence …
scattering behavior, ranging from the universal Wigner laws near 0 kelvin to the occurrence …
Imaging resonances in low-energy NO-He inelastic collisions
SN Vogels, J Onvlee, S Chefdeville, A van der Avoird… - Science, 2015 - science.org
In molecular collisions, resonances occur at specific energies at which the colliding particles
temporarily form quasibound complexes, resulting in rapid variations in the energy …
temporarily form quasibound complexes, resulting in rapid variations in the energy …
Cold and controlled chemical reaction dynamics
J Toscano, HJ Lewandowski… - Physical Chemistry …, 2020 - pubs.rsc.org
The prospect of studying state-to-state chemical reaction dynamics, with full control over all
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …
Anisotropic dynamics of resonant scattering between a pair of cold aligned diatoms
H Zhou, WE Perreault, N Mukherjee, RN Zare - Nature Chemistry, 2022 - nature.com
The collision dynamics between a pair of aligned molecules in the presence of a partial-
wave resonance provide the most sensitive probe of the long-range anisotropic forces …
wave resonance provide the most sensitive probe of the long-range anisotropic forces …
Observation of the isotope effect in sub-kelvin reactions
Quantum phenomena in the translational motion of reactants, which are usually negligible at
room temperature, can dominate reaction dynamics at low temperatures. In such cold …
room temperature, can dominate reaction dynamics at low temperatures. In such cold …
Observation of Partial Wave Resonances in Low-Energy O2–H2 Inelastic Collisions
S Chefdeville, Y Kalugina, SYT van de Meerakker… - Science, 2013 - science.org
Partial wave resonances predicted to occur in bimolecular collision processes have proven
challenging to observe experimentally. Here, we report crossed-beam experiments and …
challenging to observe experimentally. Here, we report crossed-beam experiments and …