Towards chemistry at absolute zero

BR Heazlewood, TP Softley - Nature Reviews Chemistry, 2021 - nature.com
The prospect of cooling matter down to temperatures that are close to absolute zero raises
intriguing questions about how chemical reactivity changes under these extreme conditions …

Molecular excitation in the interstellar medium: Recent advances in collisional, radiative, and chemical processes

E Roueff, F Lique - Chemical reviews, 2013 - ACS Publications
Our main knowledge about astrophysical environments relies on radiative spectra.
Absorption studies require background sources that are located hapharzadly in …

Perspective: Ultracold molecules and the dawn of cold controlled chemistry

N Balakrishnan - The Journal of chemical physics, 2016 - pubs.aip.org
Ultracold molecules offer unprecedented opportunities for the controlled interrogation of
molecular events, including chemical reactivity in the ultimate quantum regime. The …

Observation of resonances in Penning ionization reactions at sub-kelvin temperatures in merged beams

AB Henson, S Gersten, Y Shagam, J Narevicius… - Science, 2012 - science.org
Experiments have lagged theory in exploring chemical interactions at temperatures so low
that translational degrees of freedom can no longer be treated classically. The difficulty has …

Imaging the onset of the resonance regime in low-energy NO-He collisions

T de Jongh, M Besemer, Q Shuai, T Karman… - Science, 2020 - science.org
At low energies, the quantum wave–like nature of molecular interactions results in distinctive
scattering behavior, ranging from the universal Wigner laws near 0 kelvin to the occurrence …

Imaging resonances in low-energy NO-He inelastic collisions

SN Vogels, J Onvlee, S Chefdeville, A van der Avoird… - Science, 2015 - science.org
In molecular collisions, resonances occur at specific energies at which the colliding particles
temporarily form quasibound complexes, resulting in rapid variations in the energy …

Cold and controlled chemical reaction dynamics

J Toscano, HJ Lewandowski… - Physical Chemistry …, 2020 - pubs.rsc.org
The prospect of studying state-to-state chemical reaction dynamics, with full control over all
of the reaction parameters, is becoming a reality for a small number of systems. Thanks to …

Anisotropic dynamics of resonant scattering between a pair of cold aligned diatoms

H Zhou, WE Perreault, N Mukherjee, RN Zare - Nature Chemistry, 2022 - nature.com
The collision dynamics between a pair of aligned molecules in the presence of a partial-
wave resonance provide the most sensitive probe of the long-range anisotropic forces …

Observation of the isotope effect in sub-kelvin reactions

E Lavert-Ofir, Y Shagam, AB Henson, S Gersten… - Nature …, 2014 - nature.com
Quantum phenomena in the translational motion of reactants, which are usually negligible at
room temperature, can dominate reaction dynamics at low temperatures. In such cold …

Observation of Partial Wave Resonances in Low-Energy O2–H2 Inelastic Collisions

S Chefdeville, Y Kalugina, SYT van de Meerakker… - Science, 2013 - science.org
Partial wave resonances predicted to occur in bimolecular collision processes have proven
challenging to observe experimentally. Here, we report crossed-beam experiments and …