Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Transition metal complexes with bulky 4, 6-di-tert-butyl-N-aryl (alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism

AI Poddel'sky, VK Cherkasov, GA Abakumov - Coordination Chemistry …, 2009 - Elsevier
Coordination compounds based on the substituted o-iminoquinonato, o-
iminosemiquinonato and o-amidophenolato ligands with transition metal ions are described …

Assigning ligand redox levels in complexes of 2-aminophenolates: Structural signatures

R Mukherjee - Inorganic Chemistry, 2020 - ACS Publications
The purpose of this Viewpoint is to provide a broad-ranging update of advances in the
coordination chemistry of redox-active (noninnocent) 2-aminophenolates, with emphasis on …

Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3

AT Radosevich, JG Melnick, SA Stoian… - Inorganic …, 2009 - ACS Publications
The syntheses of meridionally ligated tricarbonyl complexes (PNP) Mn (CO) 3 and (PNP) Re
(CO) 3 are described (PNP=[2-P (CHMe2) 2-4-MeC6H3] 2N−). Cyclic voltammograms show …

Chemistry of Complexes of Group 14 Elements Based on Redox-Active Ligands of the o-Iminoquinone Type

MG Chegerev, AV Piskunov - Russian Journal of Coordination Chemistry, 2018 - Springer
Specific features of the synthesis and structures of the complexes of Group 14 elements (Si,
Ge, Sn, Pb) with o-iminoquinone ligands are discussed. The chemical reactions of the above …

Triphenylantimony(V) o‐amidophenolates with unsymmetrical N‐aryl group for a reversible dioxygen binding

AI Poddel'sky, YA Kurskii, AV Piskunov… - Applied …, 2011 - Wiley Online Library
New triphenylantimony (V) o‐amidophenolates (AP‐Me, Et) SbPh3 (1) and (AP‐Me, iPr)
SbPh3 (2) with unsymmetrically substituted N‐aryl groups and (AP‐Et, Et) SbPh3 (3) with …

Europium and ytterbium complexes with o-iminoquinonato ligands: synthesis, structure, and magnetic behavior

SV Klementyeva, AN Lukoyanov, MY Afonin… - Dalton …, 2019 - pubs.rsc.org
Complexes of divalent ytterbium (1) and europium (2) with a dianionic o-amidophenolate
ligand were prepared by both the direct reduction of 4, 6-di-tert-butyl-N-(2, 6 …

Preparation of new dioxygen‐active triphenylantimony (V) catecholate‐containing porous polymer

SA Chesnokov, NA Lenshina… - Applied …, 2017 - Wiley Online Library
Novel porous polymers with 4‐ethoxy‐3, 6‐di‐tert‐butyl‐o‐benzoquinone grafted to the
porous surface have been prepared via the secondary functionalization of porous polymer …

Pentacoordinated cloro-bis-o-iminosemiquinonato MnIII and FeIII complexes

AV Piskunov, KI Pashanova, IV Ershova… - Journal of Molecular …, 2018 - Elsevier
The new pentacoordinated chloro-bis-o-iminosemiquinonato complexes (imSQ OMe) 2 Mn
III Cl (1) and (imSQ OMe) 2 Fe III Cl (2) based on 4, 6-di-tert-butyl-N-(2-methoxyphenyl)-o …

Homoleptic tris-diphosphine Re (I) and Re (II) complexes and Re (II) photophysics and photochemistry

JJ Adams, N Arulsamy, BP Sullivan… - Inorganic …, 2015 - ACS Publications
The ligand-to-metal charge transfer state (LMCT) of [(dmpe) 3Re] 2+(dmpe= 1, 2-bis
(dimethylphosphino) ethane) has been demonstrated to be a potent oxidant (E 0 …