Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important
co-factors to enable binding of a dioxygen molecule so that it can be used in various …

The use of inorganic nanomaterials to tackle and exploit the intrinsic chemical nature of the
tumor microenvironment (TME) has emerged as a promising strategy in cancer therapy …

Aldehyde deformylation is an important reaction in biology, organic chemistry and inorganic
chemistry and the process has been widely applied and utilized. For instance, in biology, the …

The chemistry of copper-dioxygen complexes is relevant to copper enzymes in biology as
well as in (ligand) Cu–O2 (or Cu2–O2) species utilized in oxidative transformations. For …

Metal-dioxygen species are important intermediates formed during dioxygen activations by
metalloenzymes in various biological processes, by catalysts in fuel cells, and prior to O2 …

The reaction of [M (L)] n with H2O2 as an [O2] unit source and NEt3 as a base is a widely
used biomimetic transition metal-peroxo and-superoxo complex [M (L) O2] n− 1 synthesis …

Peroxomanganese species have been proposed as key intermediates in the catalytic cycles
of both manganese enzymes and synthetic catalysts. However, many of these intermediates …

Ligand framework in a metal complex has a pivotal role to play in orchestrating the
spectroscopic and reactivity parameters. High‐valent non‐heme metal intermediates are …

Manganese catalysts that activate hydrogen peroxide have seen increased use in organic
transformations, such as olefin epoxidation and alkane C− H bond oxidation. Proposed …

Dioxygen O–O bond activation is a process for oxygenases and oxidases to perform
biological functions and synthetic biomimetic catalysts to carry out oxygenation reactions …