Water electrolysis

AJ Shih, MCO Monteiro, F Dattila, D Pavesi… - Nature Reviews …, 2022 - nature.com
Electrochemistry has the potential to sustainably transform molecules with electrons
supplied by renewable electricity. It is one of many solutions towards a more circular …

Modeling Operando Electrochemical CO2 Reduction

F Dattila, RR Seemakurthi, Y Zhou, N López - Chemical Reviews, 2022 - ACS Publications
Since the seminal works on the application of density functional theory and the
computational hydrogen electrode to electrochemical CO2 reduction (eCO2R) and …

Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution

MCO Monteiro, F Dattila, B Hagedoorn… - Nature Catalysis, 2021 - nature.com
The electrocatalytic reduction of carbon dioxide is widely studied for the sustainable
production of fuels and chemicals. Metal ions in the electrolyte influence the reaction …

Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis

SJ Cobb, VM Badiani, AM Dharani, A Wagner… - Nature …, 2022 - nature.com
The performance of heterogeneous catalysts for electrocatalytic CO2 reduction suffers from
unwanted side reactions and kinetic inefficiencies at the required large overpotential …

[HTML][HTML] Measuring local pH in electrochemistry

MCO Monteiro, MTM Koper - Current opinion in electrochemistry, 2021 - Elsevier
Localized pH measurements are important in various areas of electrochemistry, from
corrosion to bio-electrochemistry and electrocatalysis. Different techniques are available to …

Time-Resolved Local pH Measurements during CO2 Reduction Using Scanning Electrochemical Microscopy: Buffering and Tip Effects

MCO Monteiro, A Mirabal, L Jacobse, K Doblhoff-Dier… - Jacs Au, 2021 - ACS Publications
The electrochemical reduction of CO2 is widely studied as a sustainable alternative for the
production of fuels and chemicals. The electrolyte's bulk pH and composition play an …

Pathways for the Formation of C2+ Products under Alkaline Conditions during the Electrochemical Reduction of CO2

JA Gauthier, Z Lin, M Head-Gordon, AT Bell - ACS Energy Letters, 2022 - ACS Publications
Establishing how Cu facilitates the electrochemical CO2 reduction reaction (CO2RR) to C2+
products remains a critical challenge. Under typical reaction conditions, the pH near the …

Interfacial pH measurements during CO 2 reduction on gold using a rotating ring-disk electrode

X Liu, MCO Monteiro, MTM Koper - Physical Chemistry Chemical …, 2023 - pubs.rsc.org
Insights into how to control the activity and selectivity of the electrochemical CO2 reduction
reaction are still limited because of insufficient knowledge of the reaction mechanism and …

[HTML][HTML] Cathodic corrosion: 21st century insights into a 19th century phenomenon

TJP Hersbach, MTM Koper - Current Opinion in Electrochemistry, 2021 - Elsevier
Cathodic corrosion is an enigmatic electrochemical process that etches metallic electrodes
at potentials below 0 Volt versus the normal hydrogen electrode. Though this phenomenon …

Probing the local reaction environment during high turnover carbon dioxide reduction with ag‐based gas diffusion electrodes

S Dieckhöfer, D Öhl, JRC Junqueira… - … A European Journal, 2021 - Wiley Online Library
Discerning the influence of electrochemical reactions on the electrode microenvironment is
an unavoidable topic for electrochemical reactions that involve the production of OH− and …