Recent Advances in Pd‐Catalyzed Reactions Involving the “On‐Water” Mechanism

D Wei, GQ Lin - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary As the chemical industry grapples with the need for more eco‐
friendly practices, the use of water as a reaction medium is gaining attraction in organic …

Cu (ii)-catalyzed 'in-water'N-arylation of electron-deficient NH-heterocycles

S Sunny, M Maingle, L Sheeba, FR Pathan… - Green …, 2024 - pubs.rsc.org
Cu (II)-catalyzed N-arylation of electron-deficient NH-heterocycles 'in-water'at room
temperature is described. A wide substrate scope with respect to structural and electronic …

Heme‐Enzymatic Biocatalysis for C− C or C− N Bond Formation

H Weng, M Huang - ChemCatChem, 2024 - Wiley Online Library
Abstract The C− C or C− N bond formation is critical in the synthesis of pharmaceuticals and
other value‐added products; however, traditional metal‐catalysed synthesis has brought …

“In-Water” Three-Component One-Pot Reaction for the Facile Synthesis of Densely Functionalized 2,3-Dihydro-1H-pyrrol-2-ols and Mechanistic Insight

Saigal, N Sudheer, SC Sahoo, MM Khan… - ACS Sustainable …, 2024 - ACS Publications
An environmentally friendly multicomponent reaction strategy for the synthesis of functionally
rich all-carbon substituted 2, 3-dihydro-1 H-pyrrol-2-ols “in-water” at room temperature has …

Efficient Synthesis of Benzimidazole and Quinoline Derivatives Catalyzed by Functionalized Amidato Ruthenium Complexes in Water via Acceptorless …

X Liu, WZ Dong, Y Liu, WY Shao, Y Li, X Yu… - …, 2023 - Wiley Online Library
Transition‐metal‐catalyzed acceptorless dehydrogenative coupling (ADC) has emerged as
a sustainable synthetic strategy for the construction of N‐heteroaromatics. Herein, a series of …

Stereoselective construction of tertiary homoallyl alcohols and ethers by nucleophilic substitution at quaternary carbon stereocenters

X Chen, K Patel, I Marek - Angewandte Chemie, 2023 - Wiley Online Library
An efficient method for the stereoselective construction of tertiary C− O bonds via a
stereoinvertive nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl …

Transforming Non-innocent Phenalenyl to a Potent Photoreductant: Captivating Reductive Functionalization of Aryl Halides through Visible-Light-Induced Electron …

V Pathania, VJ Roy, SR Roy - The Journal of Organic Chemistry, 2022 - ACS Publications
Herein, we have established a phenalenyl-based molecular scaffold which serves as a
potent photoreductant utilizing the empty NBMO in the presence of a base to form a radical …

[HTML][HTML] Knoevenagel condensation reaction in supercritical carbon dioxide medium using a Zn (II) coordination polymer as catalyst

NR Conceicao, BP Nobre, A Karmakar… - Inorganica Chimica …, 2022 - Elsevier
The replacement of conventional organic solvents by the so-called “green solvents” is a
usual approach to more sustainable chemical processes. Supercritical carbon dioxide …

[HTML][HTML] Novel cyano-activated Cu (ii) complexes of arylhydrazones of active methylene nitriles and their catalytic application for azide–alkyne cycloaddition in water …

AV Gurbanov, AG Mahmoud, VA Aliyeva… - New Journal of …, 2023 - pubs.rsc.org
The reaction of 2-(2-(dicyanomethylene) hydrazineyl) benzoic acid (H2L1) with copper (II)
acetate in the absence or presence of imidazole (im), 4, 4′-bipyridine (4, 4′-bipy) or …

[HTML][HTML] Na2 [Pd (saccharinate) 4]: A new phosphine-free water-soluble catalyst with singular structure for modification of ribose nucleosides at room temperature

JL Serrano, J Pérez, JA Pérez, I da Silva, R Sahu, K Pal… - Catalysis Today, 2024 - Elsevier
The easy synthesis of the anionic palladium catalyst containing saccharinate as only ligand
Na 2 [Pd (saccharinate) 4](I), starting from either Na 2 [PdCl 4] or Pd (AcO) 2, is reported …