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Recent Advances in Pd‐Catalyzed Reactions Involving the “On‐Water” Mechanism†
D Wei, GQ Lin - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary As the chemical industry grapples with the need for more eco‐
friendly practices, the use of water as a reaction medium is gaining attraction in organic …
friendly practices, the use of water as a reaction medium is gaining attraction in organic …
Cu (ii)-catalyzed 'in-water'N-arylation of electron-deficient NH-heterocycles
Cu (II)-catalyzed N-arylation of electron-deficient NH-heterocycles 'in-water'at room
temperature is described. A wide substrate scope with respect to structural and electronic …
temperature is described. A wide substrate scope with respect to structural and electronic …
Heme‐Enzymatic Biocatalysis for C− C or C− N Bond Formation
H Weng, M Huang - ChemCatChem, 2024 - Wiley Online Library
Abstract The C− C or C− N bond formation is critical in the synthesis of pharmaceuticals and
other value‐added products; however, traditional metal‐catalysed synthesis has brought …
other value‐added products; however, traditional metal‐catalysed synthesis has brought …
“In-Water” Three-Component One-Pot Reaction for the Facile Synthesis of Densely Functionalized 2,3-Dihydro-1H-pyrrol-2-ols and Mechanistic Insight
An environmentally friendly multicomponent reaction strategy for the synthesis of functionally
rich all-carbon substituted 2, 3-dihydro-1 H-pyrrol-2-ols “in-water” at room temperature has …
rich all-carbon substituted 2, 3-dihydro-1 H-pyrrol-2-ols “in-water” at room temperature has …
Efficient Synthesis of Benzimidazole and Quinoline Derivatives Catalyzed by Functionalized Amidato Ruthenium Complexes in Water via Acceptorless …
X Liu, WZ Dong, Y Liu, WY Shao, Y Li, X Yu… - …, 2023 - Wiley Online Library
Transition‐metal‐catalyzed acceptorless dehydrogenative coupling (ADC) has emerged as
a sustainable synthetic strategy for the construction of N‐heteroaromatics. Herein, a series of …
a sustainable synthetic strategy for the construction of N‐heteroaromatics. Herein, a series of …
Stereoselective construction of tertiary homoallyl alcohols and ethers by nucleophilic substitution at quaternary carbon stereocenters
An efficient method for the stereoselective construction of tertiary C− O bonds via a
stereoinvertive nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl …
stereoinvertive nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl …
Transforming Non-innocent Phenalenyl to a Potent Photoreductant: Captivating Reductive Functionalization of Aryl Halides through Visible-Light-Induced Electron …
Herein, we have established a phenalenyl-based molecular scaffold which serves as a
potent photoreductant utilizing the empty NBMO in the presence of a base to form a radical …
potent photoreductant utilizing the empty NBMO in the presence of a base to form a radical …
[HTML][HTML] Knoevenagel condensation reaction in supercritical carbon dioxide medium using a Zn (II) coordination polymer as catalyst
The replacement of conventional organic solvents by the so-called “green solvents” is a
usual approach to more sustainable chemical processes. Supercritical carbon dioxide …
usual approach to more sustainable chemical processes. Supercritical carbon dioxide …
[HTML][HTML] Novel cyano-activated Cu (ii) complexes of arylhydrazones of active methylene nitriles and their catalytic application for azide–alkyne cycloaddition in water …
The reaction of 2-(2-(dicyanomethylene) hydrazineyl) benzoic acid (H2L1) with copper (II)
acetate in the absence or presence of imidazole (im), 4, 4′-bipyridine (4, 4′-bipy) or …
acetate in the absence or presence of imidazole (im), 4, 4′-bipyridine (4, 4′-bipy) or …
[HTML][HTML] Na2 [Pd (saccharinate) 4]: A new phosphine-free water-soluble catalyst with singular structure for modification of ribose nucleosides at room temperature
The easy synthesis of the anionic palladium catalyst containing saccharinate as only ligand
Na 2 [Pd (saccharinate) 4](I), starting from either Na 2 [PdCl 4] or Pd (AcO) 2, is reported …
Na 2 [Pd (saccharinate) 4](I), starting from either Na 2 [PdCl 4] or Pd (AcO) 2, is reported …