Metal coordinated macrocyclic complexes in different chemical transformations

MS Thakur, N Singh, A Sharma, R Rana… - Coordination Chemistry …, 2022 - Elsevier
Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for
designing new molecules with inherently selective properties. Metal coordinated …

An insight into the concept of neuroinflammation and neurodegeneration in Alzheimer's disease: Targeting molecular approach Nrf2, NF-κB, and CREB

S Bhardwaj, AK Grewal, S Singh, V Dhankar… - …, 2024 - Springer
Alzheimer's disease (AD) is a most prevalent neurologic disorder characterized by cognitive
dysfunction, amyloid-β (Aβ) protein accumulation, and excessive neuroinflammation. It …

Oxido-molybdenum (V) corroles as robust catalysts for oxidative bromination and selective epoxidation reactions in aqueous media under mild conditions

I Yadav, V Prakash, MR Maurya, M Sankar - Inorganic Chemistry, 2023 - ACS Publications
Two new meso-substituted oxido-molybdenum corroles were synthesized and characterized
by various spectroscopic techniques. In the thermogram, MoO [TTC](1) exhibited excellent …

Unsymmetrically β-functionalized π-extended porphyrins: synthesis, spectral, electrochemical redox properties, and their utilization as efficient two-photon absorbers

AS Bulbul, N Chaudhri, M Shanu, JN Acharyya… - Inorganic …, 2022 - ACS Publications
Two new series of unsymmetrically β-functionalized porphyrins, MTPP (NO2) MA (1M),(MA=
methyl acrylate) and MTPP (NO2) MB (2M)(MB= mono-benzo)(where M= 2H, Co (II), Ni (II) …

A novel polyoxovanadate-based Co-MOF: highly efficient and selective oxidation of a mustard gas simulant by two-site synergetic catalysis

HR Tian, Z Zhang, SM Liu, TY Dang, XH Li… - Journal of Materials …, 2020 - pubs.rsc.org
Two novel polyoxovanadate-based metal–organic frameworks (MOFs),[Co (bib)]{V2O6}(V–
Co-MOF) and [Ni (en)(bib)]{V2O6}· 2H2O (V–Ni-MOF)(bib= 1, 4-bis (1H-imidazoly-1-yl) …

Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity

R Kumar, V Prakash, M Sankar - Inorganic Chemistry, 2024 - ACS Publications
Two new vanadyl complexes of N-confused porphyrins (NCPs),[VONCTPP](V-1) and
[VONCP (OMe) 8](V-2), have been synthesized for the first time and investigated as a …

Facile Synthesis of β-Tetracyano Vanadyl Porphyrin from Its Tetrabromo Analogue and Its Excellent Catalytic Activity for Bromination and Epoxidation Reactions

MR Maurya, V Prakash, TA Dar, M Sankar - ACS omega, 2023 - ACS Publications
Complex 2, 3, 12, 13-tetracyano-5, 10, 15, 20-tetraphenylporphyrinatooxidovanadium
(IV){[VIVOTPP (CN) 4], 2} has been prepared by nucleophilic substitution of β-bromo groups …

Synthesis, Structural, Electrochemical, and DFT Studies of Highly Substituted Nonplanar Ni (II) Porphyrins and Their Intensity-Dependent Third-Order Nonlinear …

AS Bulbul, A Kuriakose, Komal, Reena… - Inorganic …, 2024 - ACS Publications
We designed and successfully synthesized highly substituted electron-deficient nonplanar
Ni (II) porphyrins and their derivatives (1–7) in moderate to good yields. These derivatives …

Unsymmetrical β-functionalized 'push–pull'porphyrins: synthesis and photophysical, electrochemical and nonlinear optical properties

P Rathi, S Kumar, D Banerjee, VR Soma… - Dalton …, 2020 - pubs.rsc.org
Two new series of β-triphenylamine-appended porphyrins (MTPP (TPA) 2X,(where M= 2H,
Co (II), Ni (II), Cu (II), Zn (II) and X= NO2/CHO) have been synthesized and characterized by …

Bromide oxidation: A safe strategy for electrophilic brominations

R Van Kerrebroeck, T Horsten… - European Journal of …, 2022 - Wiley Online Library
Bromination of organic substances is still an important reaction in modern synthetic
chemistry. In view of the increasing demand for sustainable synthetic chemistry, oxidative …