Ion transport in polymeric ionic liquids: recent developments and open questions

V Ganesan - Molecular Systems Design & Engineering, 2019 - pubs.rsc.org
Polymeric ionic liquids (PILs) are an emerging class of materials that combine the attractive
properties of ionic liquids with the sequence complexity and mechanical characteristics of …

Modeling and simulations of polymers: a roadmap

TE Gartner III, A Jayaraman - Macromolecules, 2019 - ACS Publications
Molecular modeling and simulations are invaluable tools for the polymer science and
engineering community. These computational approaches enable predictions and provide …

Toughening elastomers using mussel-inspired iron-catechol complexes

E Filippidi, TR Cristiani, CD Eisenbach, JH Waite… - Science, 2017 - science.org
Materials often exhibit a trade-off between stiffness and extensibility; for example,
strengthening elastomers by increasing their cross-link density leads to embrittlement and …

Decoupling ion transport and matrix dynamics to make high performance solid polymer electrolytes

SD Jones, J Bamford, GH Fredrickson… - ACS polymers …, 2022 - ACS Publications
Transport of ions through solid polymeric electrolytes (SPEs) involves a complicated
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …

Selective ion transport through hydrated micropores in polymer membranes

A Wang, C Breakwell, F Foglia, R Tan, L Lovell, X Wei… - Nature, 2024 - nature.com
Ion-conducting polymer membranes are essential in many separation processes and
electrochemical devices, including electrodialysis, redox flow batteries, fuel cells and …

The role of backbone polarity on aggregation and conduction of ions in polymer electrolytes

NS Schauser, DJ Grzetic, T Tabassum… - Journal of the …, 2020 - ACS Publications
The usual understanding in polymer electrolyte design is that an increase in the polymer
dielectric constant results in reduced ion aggregation and therefore increased ionic …

Soft matter roadmap

JL Barrat, E Del Gado, SU Egelhaaf… - Journal of Physics …, 2023 - iopscience.iop.org
Soft materials are usually defined as materials made of mesoscopic entities, often self-
organised, sensitive to thermal fluctuations and to weak perturbations. Archetypal examples …

Impact of hydration and sulfonation on the morphology and ionic conductivity of sulfonated poly (phenylene) proton exchange membranes

EG Sorte, BA Paren, CG Rodriguez, C Fujimoto… - …, 2019 - ACS Publications
Multiple computational and experimental techniques are used to understand the nanoscale
morphology and water/proton transport properties in a series of sulfonated Diels–Alder poly …

Percolated ionic aggregate morphologies and decoupled ion transport in precise sulfonated polymers synthesized by ring-opening metathesis polymerization

BA Paren, BA Thurston, WJ Neary, A Kendrick… - …, 2020 - ACS Publications
We describe a set of precise single-ion conducting polymers that form self-assembled
percolated ionic aggregates in glassy polymer matrices and have decoupled transport of …

Ion pairing and the structure of gel coacervates

SPO Danielsen, S Panyukov, M Rubinstein - Macromolecules, 2020 - ACS Publications
A scaling model for the structure of coacervates is presented for mixtures of oppositely
charged polyelectrolytes of both symmetric and asymmetric charge densities for different …