Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching

J Li, A Kumar, BA Johnson, S Ott - Nature Communications, 2023 - nature.com
Electric conductivity in metal-organic frameworks (MOFs) follows either a band-like or a
redox-hop** charge transport mechanism. While conductivity by the band-like mechanism …

Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications

AA Berseneva, HC zur Loye - Crystal Growth & Design, 2023 - ACS Publications
Chalcogenide-containing materials are important for the semiconductor and thermoelectric
industries and are up-and-coming materials for superconductors, catalysis, and battery …

All-Inorganic Open-Framework Chalcogenides, A3Ga5S9·xH2O (A = Rb and Cs), Exhibiting Ultrafast Uranyl Remediation and Illustrating a Novel Post …

AA Berseneva, M Aziziha, J Schorne-Pinto… - Chemistry of …, 2022 - ACS Publications
Fast and effective uranyl sequestration is of interest to the nuclear industry. Recently,
layered chalcogenide materials have demonstrated fast, selective, and efficient sorption …

Electrically conductive [Fe 4 S 4]-based organometallic polymers

K Kadota, T Chen, EL Gormley, CH Hendon… - Chemical …, 2023 - pubs.rsc.org
Tailoring the molecular components of hybrid organic–inorganic materials enables precise
control over their electronic properties. Designing electrically conductive coordination …

Computational quantum chemistry of metal–organic frameworks

I Choudhuri, J Ye, DG Truhlar - Chemical Physics Reviews, 2023 - pubs.aip.org
Metal–organic frameworks (MOFs) have premium exceptional properties for a variety of
functions, such as gas separation and storage and catalysis. The large variety of possible …

Solvent-controlled ion-coupled charge transport in microporous metal chalcogenides

J McKenzie, PA Kempler, CK Brozek - Chemical Science, 2022 - pubs.rsc.org
Interactions between ions and itinerant charges govern electronic processes ranging from
the redox chemistry of molecules to the conductivity of organic semiconductors, but remain …