Dioxygen activation by nonheme diiron enzymes: diverse dioxygen adducts, high-valent intermediates, and related model complexes

AJ Jasniewski, L Que Jr - Chemical Reviews, 2018 - ACS Publications
A growing subset of metalloenzymes activates dioxygen with nonheme diiron active sites to
effect substrate oxidations that range from the hydroxylation of methane and the …

Supported single atoms as new class of catalysts for electrochemical reduction of carbon dioxide

Y Cheng, S Yang, SP Jiang, S Wang - Small Methods, 2019 - Wiley Online Library
Carbon dioxide (CO2) emitted from excess consumption of fossil fuels leads to the rise of
CO2 concentrations in the atmosphere. One of the most attractive solutions to cut CO2 …

Ethanol‐Induced Ni2+‐Intercalated Cobalt Organic Frameworks on Vanadium Pentoxide for Synergistically Enhancing the Performance of 3D‐Printed Micro …

H Zhou, G Zhu, S Dong, P Liu, Y Lu, Z Zhou… - Advanced …, 2023 - Wiley Online Library
The synthesis of metal‐organic framework (MOF) nanocomposites with high energy density
and excellent mechanical strength is limited by the degree of lattice matching and crystal …

Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH

J Ding, Z Wei, F Li, J Zhang, Q Zhang, J Zhou… - Nature …, 2023 - nature.com
In this work, via engineering the conformation of cobalt active center in cobalt
phthalocyanine molecular catalyst, the catalytic efficiency of electrochemical carbon …

Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis

L Bai, CS Hsu, DTL Alexander, HM Chen, X Hu - Nature Energy, 2021 - nature.com
The oxygen evolution reaction (OER) is an essential anode reaction for the generation of
fuels through water splitting or CO2 electroreduction. Mixed metal oxides containing Co, Fe …

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

HB Yang, SF Hung, S Liu, K Yuan, S Miao, L Zhang… - Nature energy, 2018 - nature.com
Electrochemical reduction of CO2 to chemical fuel offers a promising strategy for managing
the global carbon balance, but presents challenges for chemistry due to the lack of effective …

Nitrogen Vacancy Induced Coordinative Reconstruction of Single‐Atom Ni Catalyst for Efficient Electrochemical CO2 Reduction

C Jia, S Li, Y Zhao, RK Hocking, W Ren… - Advanced Functional …, 2021 - Wiley Online Library
Transition metal nitrogen carbon based single‐atom catalysts (SACs) have exhibited
superior activity and selectivity for CO2 electroreduction to CO. A favorable local nitrogen …

Tracking the Evolution of Single-Atom Catalysts for the CO2 Electrocatalytic Reduction Using Operando X-ray Absorption Spectroscopy and Machine Learning

A Martini, D Hursán, J Timoshenko… - Journal of the …, 2023 - ACS Publications
Transition metal-nitrogen-doped carbons (TMNCs) are a promising class of catalysts for the
CO2 electrochemical reduction reaction. In particular, high CO2-to-CO conversion activities …

Template-Sacrificing Synthesis of Well-Defined Asymmetrically Coordinated Single-Atom Catalysts for Highly Efficient CO2 Electrocatalytic Reduction

M Huang, B Deng, X Zhao, Z Zhang, F Li, K Li, Z Cui… - ACS …, 2022 - ACS Publications
Although various single-atom catalysts have been designed, atomically engineering their
coordination environment remains a great challenge. Herein, a one-pot template-sacrificing …