Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Dihydrogen and Ethylene Activation by a Sterically Distorted Distibene
Y Pang, M Leutzsch, N Nöthling… - Angewandte Chemie …, 2023 - Wiley Online Library
Herein, we report the synthesis of a sterically distorted distibene ([4] 2) and its transition‐
metal‐like reactivity towards two fundamental feedstock chemicals: H2 and ethylene …
metal‐like reactivity towards two fundamental feedstock chemicals: H2 and ethylene …
Hydrostibination
A rigid naphthalenediamine framework has been used to prepare antimony hydrides that
feature LUMO shapes and energies similar to those found in secondary boranes. By …
feature LUMO shapes and energies similar to those found in secondary boranes. By …
Isolation of 1, 2, 4, 3-triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) derivatives and reactivity toward CO and isonitriles
3, 4-dihydro-2 H-1, 2, 4, 3-triazaborol-3-yl-lithium 3 was synthesized and fully characterized.
The 11B NMR spectrum, X-ray diffraction analysis, and computational studies revealed the …
The 11B NMR spectrum, X-ray diffraction analysis, and computational studies revealed the …
Synthesis of bismuthanyl-substituted monomeric triel hydrides
R Szlosek, C Marquardt, O Hegen, G Balázs… - Chemical …, 2024 - pubs.rsc.org
The syntheses and characterizations of the first bismuthanylborane monomers stabilized
only by a donor in D· BH2Bi (SiMe3) 2 (D= DMAP 1a, IDipp 1b, IMe41c; DMAP= 4 …
only by a donor in D· BH2Bi (SiMe3) 2 (D= DMAP 1a, IDipp 1b, IMe41c; DMAP= 4 …
Actinide–Pnictide (An− Pn) Bonds Spanning Non‐Metal, Metalloid, and Metal Combinations (An= U, Th; Pn= P, As, Sb, Bi)
TM Rookes, EP Wildman, G Balazs… - Angewandte Chemie …, 2018 - Wiley Online Library
The synthesis and characterisation is presented of the compounds [An (TrenDMBS){Pn
(SiMe3) 2}] and [An (TrenTIPS){Pn (SiMe3) 2}][TrenDMBS= N (CH2CH2NSiMe2But) 3, An …
(SiMe3) 2}] and [An (TrenTIPS){Pn (SiMe3) 2}][TrenDMBS= N (CH2CH2NSiMe2But) 3, An …
A Mechanistic Study on Reactions of Group 13 Diyls LM with Cp*SbX2: From Stibanyl Radicals to Antimony Hydrides
Abstract Oxidative addition of Cp* SbX2 (X= Cl, Br, I; Cp*= C5Me5) to group 13 diyls LM (M=
Al, Ga, In; L= HC [C (Me) N (Dip)] 2, Dip= 2, 6‐iPr2C6H3) yields elemental antimony (M= Al) …
Al, Ga, In; L= HC [C (Me) N (Dip)] 2, Dip= 2, 6‐iPr2C6H3) yields elemental antimony (M= Al) …
Titanium‐Catalyzed Polymerization of a Lewis Base‐Stabilized Phosphinoborane
J Braese, F Lehnfeld, VT Annibale… - … A European Journal, 2023 - Wiley Online Library
The reaction of the Lewis base‐stabilized phosphinoborane monomer tBuHPBH2NMe3 (2
a) with catalytic amounts of bis (η5: η1‐adamantylidenepentafulvene) titanium (1) provides a …
a) with catalytic amounts of bis (η5: η1‐adamantylidenepentafulvene) titanium (1) provides a …
Synthesis and Application of Alkali Metal Antimonide—A New Approach to Antimony Chemistry
K Dollberg, S Schneider, RM Richter… - Angewandte Chemie …, 2022 - Wiley Online Library
Alkali metal dihydrogen‐antimonides [M (L) xSbH2], short: alkali metal antimonides (M= Li,
Na, K, Rb, Cs; 1: L= pmdta; 2: L= crown‐ether), were prepared from stibine and n …
Na, K, Rb, Cs; 1: L= pmdta; 2: L= crown‐ether), were prepared from stibine and n …
Structures and Stability of Mixed Main Group Hydrides [PBEH6]n (E = C, Si, Ge; n = 1–4) and Donor–Acceptor Stabilization of Monomeric Chain Isomers
AM Belousova, AY Timoshkin - The Journal of Physical Chemistry …, 2023 - ACS Publications
Structures and stability of mixed group 13–14–15 element hydrides PBEH6 (E= C, Si, Ge),
their oligomers, and complexes with Lewis acids and Lewis base are computationally …
their oligomers, and complexes with Lewis acids and Lewis base are computationally …