Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms
Monatomic zero-valent silicon and germanium complexes (silylones and germylones),
stabilised by neutral donating ligands, emerged only recently as a new class of low-valent …
stabilised by neutral donating ligands, emerged only recently as a new class of low-valent …
A new area in main-group chemistry: zerovalent monoatomic silicon compounds and their analogues
Conspectus Monoatomic zerovalent main-group element complexes emerged very recently
and attracted increasing attention of both theoretical and experimental chemists. In …
and attracted increasing attention of both theoretical and experimental chemists. In …
Segmented contracted error-consistent basis sets of quadruple-ζ valence quality for one-and two-component relativistic all-electron calculations
YJ Franzke, L Spiske, P Pollak… - Journal of Chemical …, 2020 - ACS Publications
Segmented contracted basis sets of quadruple-ζ quality for exact two-component (X2C)
calculations are presented for the elements H–Rn. These sets are the all-electron relativistic …
calculations are presented for the elements H–Rn. These sets are the all-electron relativistic …
The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)
Abstract The elusive plumbylone {[SiII (Xant) SiII] Pb0} 3 stabilized by the bis (silylene)
xanthene chelating ligand 1,[SiII (Xant) SiII= PhC (NtBu) 2Si (Xant) Si (NtBu) 2CPh], and its …
xanthene chelating ligand 1,[SiII (Xant) SiII= PhC (NtBu) 2Si (Xant) Si (NtBu) 2CPh], and its …
Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me3P)2(Ph3P)Rh≡E‐Ar*] (E=Sn, Pb)
M Widemann, K Eichele, H Schubert… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Tetrylidynes [(Me3P) 2 (Ph3P) Rh≡ SnAr*](10) and [(Me3P) 2 (Ph3P) Rh≡
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …
Organotetrel chalcogenide clusters: Between strong second-harmonic and white-light continuum generation
NW Rosemann, JP Eußner, E Dornsiepen… - Journal of the …, 2016 - ACS Publications
Highly directional white-light generation was recently reported for the organotin sulfide
cluster [(StySn) 4S6](Sty= p-styryl). This effect was tentatively attributed to the amorphous …
cluster [(StySn) 4S6](Sty= p-styryl). This effect was tentatively attributed to the amorphous …
Heavier congeners of CO and CO 2 as ligands: from zero-valent germanium ('germylone') to isolable monomeric GeX and GeX 2 complexes (X= S, Se, Te)
In contrast to molecular CO and CO2, their heavier mono-and dichalcogenide homologues,
EX and EX2 (E= Si, Ge, Sn, Pb; X= O, S, Se, Te), are important support materials (eg, SiO2) …
EX and EX2 (E= Si, Ge, Sn, Pb; X= O, S, Se, Te), are important support materials (eg, SiO2) …
[Hg4Te8(Te2)4]8−: A Heavy Metal Porphyrinoid Embedded in a Lamellar Structure
C Donsbach, K Reiter, D Sundholm… - Angewandte Chemie …, 2018 - Wiley Online Library
The use of ionic liquids (CnC1Im)[BF4] with long alkyl chains (n= 10, 12) in the ionothermal
treatment of Na2 [HgTe2] led to lamellar crystal structures with molecular macrocyclic anions …
treatment of Na2 [HgTe2] led to lamellar crystal structures with molecular macrocyclic anions …
Barium sulfide under pressure: Discovery of metastable polymorphs and investigation of electronic properties on ab initio level
Barium sulfide (BaS) is an important precursor to other barium compounds with applications
from ceramics and flame retardants to luminous paints and additives, and recent research …
from ceramics and flame retardants to luminous paints and additives, and recent research …
Taming Silicon Congeners of CO and CO2: Synthesis of Monomeric SiII and SiIV Chalcogenide Complexes
A Burchert, R Müller, S Yao, C Schattenberg… - Angewandte …, 2017 - Wiley Online Library
The synthesis of the unprecedented monomeric SiII selenide complex (bis‐NHC) Si= Se→
GaCl3 2 (bis‐NHC= bis‐N heterocyclic carbene, H2C [{NC (H)= C (H) N (Dipp)} C:] 2, Dipp …
GaCl3 2 (bis‐NHC= bis‐N heterocyclic carbene, H2C [{NC (H)= C (H) N (Dipp)} C:] 2, Dipp …