In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Pincer complexes are becoming increasingly important for organometallic chemistry and
organic synthesis. Since numerous applications for such catalysts have been developed in …

Here we describe the discovery of a new class of C–H borylation catalysts and their use for
regioselective C–H borylation of aromatic, heteroaromatic, and aliphatic systems. The new …

With the aid of high-throughput screening, the efficiency of Ir-catalyzed C–H borylations has
been assessed as functions of precatalyst, boron reagent, ligand, order of addition …

Rh–N-heterocyclic carbene compounds [Rh (μ-Cl)(IPr)(η2-olefin)] 2 and RhCl (IPr)(py)(η2-
olefin)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-carbene, py= pyridine, olefin …

An unexpected borylation of organic halides with a silyborane in the presence of an alkoxy
base has been observed. This formal nucleophilic boryl substitution can be applied to a …

The square-planar monohydride complex RhH {xant (PiPr2) 2}(1; xant (PiPr2) 2= 9, 9-
dimethyl-4, 5-bis (diisopropylphosphino) xanthene) activates C–H bonds of arenes. Heating …

Organometallic compounds [Cp* Ir (κ2-N, O) X](κ2-N, O= 2-pyridinecarboxylic acid, ion (−
1)(1), 2, 4-pyridinedicarboxylic acid, ion (− 1)(2), 2, 6-pyridinedicarboxylic acid, ion (− 1)(3); …

Carbon–hydrogen bond activation of arenes by the pincer Ir (III) acetate complex (phebox) Ir
(OAc) 2 (H2O)(1; phebox= bis (oxazolinyl) phenyl) proceeded at 100° C to give the …

The catalytic activity in the hydrosilylation of terminal alkynes by the unsaturated hydrido
iridium (III) compound [IrH (κ3-hqca)(coe)](1), which contains the rigid asymmetrical …