Size-, Mass-, and Density-Controlled Preparation of TiO2 Nanoparticles in a Spherical Coordination Template

T Ichijo, S Sato, M Fujita - Journal of the American Chemical …, 2013‏ - ACS Publications
TiO2 nanoparticles were prepared with strict control of the size, molecular mass (PDI= 1.02),
and mass density by hydrolyzing a precursor, Ti (acac) 2 (biphen), in the presence of a well …

Electrochemical and density functional theory modeled reduction of enolized 1, 3-diketones

A Kuhn, KG Von Eschwege, J Conradie - Electrochimica acta, 2011‏ - Elsevier
Cathodic peak potentials (E pc) of ten enolized 1, 3-substituted 1, 3-diketones, R 1 COCHC
(OH) R 2 derivatives containing electron withdrawing and/or electron donating groups, were …

Synthesis, Electrochemical and DFT study of octahedral bis (β-diketonato)-titanium (IV) complexes

A Kuhn, J Conradie - Inorganica Chimica Acta, 2016‏ - Elsevier
The synthesis and electrochemistry of seven new and four known bis (β-diketonato)-titanium
(IV) complexes are reported. Integrated electrochemical and quantum chemistry techniques …

Electrochemical and Theoretical Modelled Reduction of β‐Diketone Inspired Chalcones

D Izuchukwu Ugwu, J Conradie - ChemistrySelect, 2024‏ - Wiley Online Library
The growing interest in synthesizing electrochemically active organic ligands stems from
extensive reports highlighting the applications of redox‐active organic molecules. These …

Gauging electronic dissymmetry in bis-chelates of titanium (iv) using sterically and electronically variable 2, 2′-biphenoxides

N Kongprakaiwoot, M Quiroz-Guzman, AG Oliver… - Chemical …, 2011‏ - pubs.rsc.org
3, 3′, 5, 5′-Tetrasubstituted-2, 2′-biphenolate complexes of titanium (IV) with bis
(diketonate)(Bob), bis (hydroxamate)(Hox) and mixed diketonate–hydroxamate (Hob) …

Structure, substitution and hydrolysis of Bis (trifluorobenzoylacetonato-O, O′) dichloro titanium (IV): An experimental and computational study

A Kuhn, S Tischlik, KH Hopmann, M Landman… - Inorganica Chimica …, 2016‏ - Elsevier
The chlorine coordinated ligands in [Ti (tfba) 2 Cl 2](Htfba= 4, 4, 4-trifluoro-1-(phenyl)-1, 3-
butanedione= PhCOCH 2 COCF 3) are very susceptible to hydrolysis and even with trace …

Observed hydrolysis of fluorine substituted bis (β-diketonato)-dichlorotitanium (IV) complexes

A Kuhn, J Conradie - Dalton Transactions, 2015‏ - pubs.rsc.org
Novel fluorine substituted mononuclear Ti (β-diketonato) 2Cl2 complexes have been
synthesised and shown to be involved in a partial hydrolysis reaction in solution, in which …

X-ray and electronic structure of tris (benzoylacetonato-κ2O, O′) iron (III)

MM Conradie, PH van Rooyen, J Conradie - Journal of Molecular Structure, 2016‏ - Elsevier
Solid state crystal data of d 5 tris (benzoylacetonato-κ 2 O, O′) iron (III),[Fe (ba) 3], are
presented. The mer isomer crystallized in the solid state. Density functional theory …

A series of alternating Na+/M 3+(M= Mn, Fe) covalent and ionic chains

N Berg, LF Jones - CrystEngComm, 2011‏ - pubs.rsc.org
We report the synthesis and full characterisation of a family of chains each exhibiting an
alternating [M–Na–M–] n (M= Mn3+ or Fe3+) 1-D topology linked via the 2, 2′-biphenol …

[PDF][PDF] Electrochemical and Theoretical Modelled Reduction of β-Diketone Inspired Chalcones

DI Ugwu, J Conradie - 2024‏ - d-nb.info
The growing interest in synthesizing electrochemically active organic ligands stems from
extensive reports highlighting the applications of redox-active organic molecules. These …