In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Metal oxide clusters, especially transition-metal polyoxometalates, have been studied for
decades because they provide a rare opportunity to study nanoscale materials with well …

While the d0 transition-metal POMs of Group V (V5+, Nb5+, Ta5+) and Group VI (Mo6+,
W6+) have been known for more than a century, the actinyl peroxide POMs, specifically …

Uranyl peroxide clusters containing from 16 to 124 uranyl ions self-assemble in aqueous
solution and exhibit tremendous topological complexity. Most of these clusters are cages …

The Fukushima-Daiichi nuclear accident brought together compromised irradiated fuel and
large amounts of seawater in a high radiation field. Based on newly acquired …

The storage of spent nuclear fuels for long periods of time in geological repositories is one
proposed solution to the stewardship of legacy, current and future nuclear waste. Recent …

The elements of groups 5 and 6, especially vanadium, molybdenum, and tungsten in their
highest oxidation states, form a vast range of polyoxoanions that can incorporate most other …

Spectator ions have known and emerging roles in aqueous metal‐cation chemistry,
respectively directing solubility, speciation, and reactivity. Here, we isolate and structurally …

Room temperature calorimetry methods were developed to describe the energy landscapes
of six polyoxometalates (POMs), Li–U24, Li–U28, K–U28, Li/K–U60, Mo132, and Mo154, in …

For 11 years now, the structural diversity and aesthetic beauty of uranyl–peroxide capsules
have fascinated researchers from the diverse fields of mineralogy, polyoxometalate …