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Free radical lipid peroxidation: mechanisms and analysis
Oxygen is indispensable to metabolism and energy production for almost all life forms.
However, reactive oxygen species (ROS) generated from life processes can cause damage …
However, reactive oxygen species (ROS) generated from life processes can cause damage …
Thermochemistry of proton-coupled electron transfer reagents and its implications
Many, if not most, redox reactions are coupled to proton transfers. This includes most
common sources of chemical potential energy, from the bioenergetic processes that power …
common sources of chemical potential energy, from the bioenergetic processes that power …
Identification of alkoxy radicals as hydrogen atom transfer agents in Ce-catalyzed C–H functionalization
Q An, YY **ng, R Pu, M Jia, Y Chen, A Hu… - Journal of the …, 2022 - ACS Publications
The intermediacy of alkoxy radicals in cerium-catalyzed C–H functionalization via H-atom
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …
Benzylic C–H esterification with limiting C–H substrate enabled by photochemical redox buffering of the Cu catalyst
Copper-catalyzed radical-relay reactions provide a versatile strategy for selective C–H
functionalization; however, reactions with peroxide-based oxidants often require excess C …
functionalization; however, reactions with peroxide-based oxidants often require excess C …
Cerium-catalyzed C–H functionalizations of alkanes utilizing alcohols as hydrogen atom transfer agents
Q An, Z Wang, Y Chen, X Wang, K Zhang… - Journal of the …, 2020 - ACS Publications
Modern photoredox catalysis has traditionally relied upon metal-to-ligand charge-transfer
(MLCT) excitation of metal polypyridyl complexes for the utilization of light energy for the …
(MLCT) excitation of metal polypyridyl complexes for the utilization of light energy for the …
Photosensitized membrane permeabilization requires contact-dependent reactions between photosensitizer and lipids
Although the general mechanisms of lipid oxidation are known, the chemical steps through
which photosensitizers and light permeabilize lipid membranes are still poorly understood …
which photosensitizers and light permeabilize lipid membranes are still poorly understood …
[كتاب][B] Photochemistry of organic compounds: from concepts to practice
P Klán, J Wirz - 2009 - books.google.com
Photochemistry of Organic Compounds: From Concepts to Practice provides a hands-on
guide demonstrating the underlying principles of photochemistry and, by reference to a …
guide demonstrating the underlying principles of photochemistry and, by reference to a …
[كتاب][B] Oxidation and antioxidants in organic chemistry and biology
ET Denisov, IB Afanas' ev - 2005 - taylorfrancis.com
Providing a comprehensive review of reactions of oxidation for different classes of organic
compounds and polymers, and biological processes mediated by free radicals, Oxidation …
compounds and polymers, and biological processes mediated by free radicals, Oxidation …
Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes
We report a set of rare copper-catalyzed reactions of alkanes with simple amides,
sulfonamides, and imides (ie, benzamides, tosylamides, carbamates, and phthalimide) to …
sulfonamides, and imides (ie, benzamides, tosylamides, carbamates, and phthalimide) to …
Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory
As the main constituent of natural gas, alkanes are arguably Nature's most plentiful organic
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …