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Recent advances in stable main group element radicals: preparation and characterization
Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …
novel physicochemical properties play significant roles not only in fundamental chemistry …
Tuning the Electronic Properties of Main-Group Species by N-Heterocyclic Vinyl (NHV) Scaffolds
Conspectus Molecules and materials with easily tunable electronic structures and properties
are at the forefront of contemporary research. π-Conjugation is fundamental in organic …
are at the forefront of contemporary research. π-Conjugation is fundamental in organic …
N-Heterocyclic Carbene-Derived Carbon Disulfide Radical Ligands for Palladium Diradicals
N-heterocyclic carbenes (NHCs) are recognized for their ability to stabilize various main
group radicals; however, NHC-derived, sulfur-based radicals remain rare. In this study, we …
group radicals; however, NHC-derived, sulfur-based radicals remain rare. In this study, we …
Advances and recent trends in dipnictenes chemistry
Dipnictenes are molecules comprising a double bond between two Group 15 elements
(referred as pnictogens (Pn)= P, As, Sb, Bi). Over the last decades, the chemistry of …
(referred as pnictogens (Pn)= P, As, Sb, Bi). Over the last decades, the chemistry of …
Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds
Phosphorus ylides are 1, 2-dipolar compounds with a negative charge on the carbon atom.
This charge is stabilized by the neighbouring onium moiety, but can also be shifted towards …
This charge is stabilized by the neighbouring onium moiety, but can also be shifted towards …
Highly stable 1, 2-dicarbonyl radical cations derived from N-heterocyclic carbenes
Stable organic radicals have been of great academic interest not only in the context of
fundamental understanding of reactive intermediates but also because of their numerous …
fundamental understanding of reactive intermediates but also because of their numerous …
Synthesis of Mesoionic N-Heterocyclic Olefins and Catalytic Application for Hydroboration Reactions
Synthesis of Mesoionic N-Heterocyclic Olefins and Catalytic Application for Hydroboration
Reactions | The Journal of Organic Chemistry Recently Viewedclose modal Pair your accounts …
Reactions | The Journal of Organic Chemistry Recently Viewedclose modal Pair your accounts …
Quantifying the electronic and steric properties of 1, 3-imidazole-based mesoionic carbenes (iMICs)
1, 3-Imidazole-based mesoionic carbenes (iMICs) are a very promising class of carbon-
donor ligands in synthesis and catalysis. However, a systematic study of the quantification of …
donor ligands in synthesis and catalysis. However, a systematic study of the quantification of …
Synthesis, structure and bonding nature of heavy dipnictene radical anions
Cyclic voltammetry (CV) studies of two L (X) Ga-substituted dipnictenes [L (R2N) GaE] 2 (E=
Sb, R= Me 1; E= Bi; R= Et 2; L= HC [C (Me) NDipp] 2; Dipp= 2, 6-i-Pr2C6H3) showed …
Sb, R= Me 1; E= Bi; R= Et 2; L= HC [C (Me) NDipp] 2; Dipp= 2, 6-i-Pr2C6H3) showed …
Synthesis of organic super-electron-donors by reaction of nitrous oxide with N-heterocyclic olefins
The reaction of nitrous oxide (N2O) with N-heterocyclic olefins (NHOs) results in cleavage of
the N–O bond and formation of azo-bridged NHO dimers. The latter represent very electron …
the N–O bond and formation of azo-bridged NHO dimers. The latter represent very electron …