Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …

The previous systems of triple‐bond and single‐bond self‐consistent, additive covalent radii,
R (AB)= r (A)+ r (B), are completed with a fit for σ2π2 double‐bonds. The primary bond …

This Feature Article seeks to present the current state of knowledge, both experimental and
theoretical, of the electronic structure and bonding in actinyl ions and related species, such …

The terminal uranium nitride linkage is a fundamental target in the study of f-orbital
participation in metal-ligand multiple bonding but has previously eluded characterization in …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

The forefront of research into the complexes of uranium reveals chemical transformations
that challenge and expand our view of this unique element. Certain ligands form multiple …

The nature and extent of covalency in uranium bonding is still unclear compared with that of
transition metals, and there is great interest in studying uranium–ligand multiple bonds …

Single atoms of uranium supported on molybdenum sulfide surfaces (U@ MoS2) have been
recently demonstrated to facilitate the hydrogen evolution reaction (HER) through …