Homogeneous and heterogeneous gold catalysis for materials science

CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

Gold-catalysed reactions of diynes

AM Asiri, ASK Hashmi - Chemical Society Reviews, 2016 - pubs.rsc.org
In this critical review the reactivity patterns observed with different types of diyne substrates
in gold catalysis are discussed. Apart from the many examples from homogeneous catalysis …

Design and catalytic asymmetric construction of axially chiral 3, 3′‐bisindole skeletons

C Ma, F Jiang, FT Sheng, Y Jiao… - Angewandte Chemie …, 2019 - Wiley Online Library
The first catalytic asymmetric construction of 3, 3′‐bisindole skeletons bearing both axial
and central chirality has been established by organocatalytic asymmetric addition reactions …

Recent advances in the synthesis of indoles from alkynes and nitrogen sources

JSS Neto, G Zeni - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …

Organocatalytic Asymmetric Annulation of ortho‐Alkynylanilines: Synthesis of Axially Chiral Naphthyl‐C2‐indoles

L Peng, K Li, C **e, S Li, D Xu, W Qin… - Angewandte Chemie …, 2019 - Wiley Online Library
A chiral Brønsted base catalyzed asymmetric annulation of ortho‐alkynylanilines has been
developed to access axially chiral naphthyl‐C2‐indoles via vinylidene ortho‐quinone …

A platinum (II)‐based molecular cage with aggregation‐induced emission for enzymatic photocyclization of alkynylaniline

Z Wei, X **g, Y Yang, J Yuan, M Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Enzymes facilitate chemical conversions through the collective activity of aggregated
components, but the marriage of aggregation‐induced emission (AIE) with molecular …

Recent Advances in Indole Synthesis and the Related Alkylation

J Ma, R Feng, ZB Dong - Asian Journal of Organic Chemistry, 2023 - Wiley Online Library
The derivatives of indoles are very useful intermediates in pharmaceuticals and organic
synthesis. The efficient synthesis of the indole blocks and related functionalizations …

A Reusable MOF‐Supported Single‐Site Zinc(II) Catalyst for Efficient Intramolecular Hydroamination of o‐Alkynylanilines

B Li, Z Ju, M Zhou, K Su, D Yuan - … Chemie International Edition, 2019 - Wiley Online Library
The exploitation of new and active earth‐abundant metal catalysts is critical for sustainable
chemical production. Herein, we demonstrate the design of highly efficient, robust, and …

Enantioselective Palladium (II)‐Catalyzed Desymmetrizative Coupling of 7‐Azabenzonorbornadienes with Alkynylanilines

J Meng, H He, Q Liu, H Xu, H Huang… - Angewandte Chemie …, 2024 - Wiley Online Library
A PdII‐catalyzed, domino enantioselective desymmetrizative coupling of 7‐
azabenzonorbornadienes with alkynylanilines is disclosed herein. This operationally simple …

Oxidative approach enables efficient access to cyclic azobenzenes

MS Maier, K Hüll, M Reynders… - Journal of the …, 2019 - ACS Publications
Azobenzenes are versatile photoswitches that have found widespread use in a variety of
fields, ranging from photopharmacology to the material sciences. In addition to regular …