Perspectives on parity violation in chiral molecules: theory, spectroscopic experiment and biomolecular homochirality
M Quack, G Seyfang, G Wichmann - Chemical Science, 2022 - pubs.rsc.org
The reflection (or 'mirror') symmetry of space is among the fundamental symmetries of
physics. It is connected to the conservation law for the quantum number parity and a …
physics. It is connected to the conservation law for the quantum number parity and a …
Roadmap on STIRAP applications
STIRAP (stimulated Raman adiabatic passage) is a powerful laser-based method, usually
involving two photons, for efficient and selective transfer of populations between quantum …
involving two photons, for efficient and selective transfer of populations between quantum …
Parity violation
R Berger, J Stohner - Wiley Interdisciplinary Reviews …, 2019 - Wiley Online Library
Violation of (space) parity in atomic physics, molecular physics and chemistry is briefly
reviewed. The review is structured by frequently asked questions related to the concept of …
reviewed. The review is structured by frequently asked questions related to the concept of …
Controlling tunneling in ammonia isotopomers
We report results of full-dimensional variational rovibrational quantum-dynamical
computations for several ammonia isotopomers, based on selected potential energy and …
computations for several ammonia isotopomers, based on selected potential energy and …
Infrared laser induced population transfer and parity selection in 14NH3: A proof of principle experiment towards detecting parity violation in chiral molecules
P Dietiker, E Miloglyadov, M Quack… - The Journal of …, 2015 - pubs.aip.org
We have set up an experiment for the efficient population transfer by a sequential two
photon—absorption and stimulated emission—process in a molecular beam to prepare …
photon—absorption and stimulated emission—process in a molecular beam to prepare …
Instanton calculations of tunneling splittings in chiral molecules
We report the ground state tunneling splittings (Δ E±) of a number of axially chiral molecules
using the ring‐polymer instanton (RPI) method (J. Chem. Phys., 2011, 134, 054109). The list …
using the ring‐polymer instanton (RPI) method (J. Chem. Phys., 2011, 134, 054109). The list …
Atomic and molecular tunneling processes in chemistry
M Quack, G Seyfang - Molecular Spectroscopy and Quantum Dynamics, 2021 - Elsevier
The article presents an overview of atomic and molecular tunneling processes, where
tunneling of “heavy” particles (ie, nuclei, not electrons) is important. After an introductory tour …
tunneling of “heavy” particles (ie, nuclei, not electrons) is important. After an introductory tour …
High resolution ro–vibrational analysis of molecules in doublet electronic states: The ν 1 fundamental of chlorine dioxide (16 O 35 Cl 16 O) in the X 2 B 1 electronic …
ON Ulenikov, ES Bekhtereva, OV Gromova… - Physical Chemistry …, 2021 - pubs.rsc.org
We report the spectrum of the ν1 fundamental of chlorine dioxide centered in the infrared
atmospheric window at 945.592 cm− 1 measured with essentially Doppler limited resolution …
atmospheric window at 945.592 cm− 1 measured with essentially Doppler limited resolution …
High resolution GHz and THz (FTIR) spectroscopy and theory of parity violation and tunneling for 1, 2-dithiine (C 4 H 4 S 2) as a candidate for measuring the parity …
We report high resolution spectroscopic results of 1, 2-dithiine-(1, 2-dithia-3, 5-
cyclohexadiene, C4H4S2) in the gigahertz and terahertz spectroscopic ranges and …
cyclohexadiene, C4H4S2) in the gigahertz and terahertz spectroscopic ranges and …
Synchrotron-Based Highest Resolution Terahertz Spectroscopy of the ν24 Band System of 1,2-Dithiine (C4H4S2): A Candidate for Measuring the Parity Violating …
The chiral C 2 symmetric molecule 1, 2-dithiine (1, 2-dithia-3, 5-hexadiene, C4H4S2) has
been identified as a possible candidate for measuring the parity violating energy difference …
been identified as a possible candidate for measuring the parity violating energy difference …