Recent Advances in Electron Donor‐Acceptor (EDA)‐Complex Reactions involving Quaternary Pyridinium Derivatives
Quaternary pyridinium compounds are valuable intermediates in organic synthesis, which
have gained immense popularity in the synthetic community. The application of transition …
have gained immense popularity in the synthetic community. The application of transition …
Radical cascade cyclization of 1, n-enynes under photo/electrochemical conditions
During the past decade, photo-and electrochemical reactions proceeding via single-electron-
transfer (SET) triggered radical pathways have emerged as an indispensable strategy for the …
transfer (SET) triggered radical pathways have emerged as an indispensable strategy for the …
Photoredox-Catalyzed 1, 4-Peroxidation–Sulfonylation of Enynones: A Three-Component Radical Coupling Approach for the Synthesis of Highly Functionalized …
D Bhatt, K Miyake, S Nakamura, HY Kim, K Oh - Organic Letters, 2024 - ACS Publications
An Eosin Y-catalyzed visible light-promoted 1, 4-peroxidation–sulfonylation of enynones
was achieved to give tetrasubstituted allenes. The photoredox catalysis of Eosin Y allowed …
was achieved to give tetrasubstituted allenes. The photoredox catalysis of Eosin Y allowed …
General electron–donor–acceptor complex mediated thioesterification reaction via site-selective C–H functionalization using aryl sulfonium Salts
Contemporary methods for synthesizing thioesters often necessitate expensive catalysts and
harsh conditions, making their synthesis from chemical feedstocks challenging. Herein, we …
harsh conditions, making their synthesis from chemical feedstocks challenging. Herein, we …
Divergent Geminal Alkynylation–Allylation and Acylation–Allylation of Carbenes: Evolution and Roles of Two Transition-Metal Catalysts
H Chen, W Yang, J Zhang, B Lu… - Journal of the American …, 2024 - ACS Publications
Cooperative bimetallic catalysis to access novel reactivities is a powerful strategy for
reaction development in transition-metal-catalyzed chemistry. Particularly, elucidation of the …
reaction development in transition-metal-catalyzed chemistry. Particularly, elucidation of the …
Mechanochemical-assisted decarboxylative sulfonylation of α, β-unsaturated carboxylic acids with sodium sulfinate salts
Develo** a green and efficient method for synthesizing vinyl sulfones is challenging and
highly desirable. We herein report a green, sustainable, and unprecedented …
highly desirable. We herein report a green, sustainable, and unprecedented …
Visible light-assisted chemistry of vinyl azides and its applications in organic synthesis
Vinyl azides have emerged as highly versatile precursors in organic synthesis due to their
rich reactivity driven by the excellent leaving-group ability of molecular nitrogen. Over the …
rich reactivity driven by the excellent leaving-group ability of molecular nitrogen. Over the …
Visible light-induced bromine radical enhanced hydrogen atom transfer (HAT) reactions in organic synthesis
Hydrogen atom transfer (HAT) reactions have gained a prominent space in organic
synthesis for allowing a straightforward approach towards CH bond activation for the …
synthesis for allowing a straightforward approach towards CH bond activation for the …
Visible light-driven α-sulfonylation of ketone-derived silyl enol ethers via an electron donor–acceptor complex
The diverse utility of β-ketosulfones in pharmaceuticals and bioactive compounds has
generated considerable interest in their synthesis. However, existing synthetic approaches …
generated considerable interest in their synthesis. However, existing synthetic approaches …
De novo synthesis of 6-6-5 fused systems through electrochemical decarboxylation and radical domino additions
C Yuan, G Liu, W Guan, J Hang, Z Fang, C Liu… - Green …, 2024 - pubs.rsc.org
Highly complex fused systems are widely present in drug development. The direct
electrosynthesis of fused systems through radical domino reactions features higher atom …
electrosynthesis of fused systems through radical domino reactions features higher atom …