Halogen-mediated conversion of hydrocarbons to commodities

R Lin, AP Amrute, J Perez-Ramirez - Chemical reviews, 2017 - ACS Publications
Halogen chemistry plays a central role in the industrial manufacture of various important
chemicals, pharmaceuticals, and polymers. It involves the reaction of halogens or halides …

Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

C Lamberti, A Zecchina, E Groppo… - Chemical Society …, 2010 - pubs.rsc.org
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …

Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts

AI Frenkel - Chemical Society Reviews, 2012 - pubs.rsc.org
Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to study
short range order in heterometallic alloys for almost four decades. In this critical review …

Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach

E Borfecchia, S Maurelli, D Gianolio… - The Journal of …, 2012 - ACS Publications
We report a careful characterization of the interaction of NH3 with the Cu (II) sites of the
[Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known …

Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine …

AA Guda, SA Guda, KA Lomachenko, MA Soldatov… - Catalysis Today, 2019 - Elsevier
In the last decade the appearance of progressively more sophisticated codes, together with
the increased computational capabilities, has made XANES a spectroscopic technique able …

Multivariate curve resolution analysis applied to time-resolved synchrotron X-ray Absorption Spectroscopy monitoring of the activation of copper alumina catalyst

WH Cassinelli, L Martins, AR Passos, SH Pulcinelli… - Catalysis Today, 2014 - Elsevier
The pure X-ray Absorption (XAS) spectral constituents and related concentration profiles
characterizing the reduction of a copper-based catalyst supported on hierarchically porous …

Probing reactive platinum sites in UiO-67 zirconium metal–organic frameworks

S Øien, G Agostini, S Svelle, E Borfecchia… - Chemistry of …, 2015 - ACS Publications
We present three methods of the synthesis of zirconium metal–organic framework UiO-67
functionalized with platinum bipyridine coordination complexes (bpydcPtIICl2 and …

X-ray absorption spectroscopies: useful tools to understand metallorganic frameworks structure and reactivity

S Bordiga, F Bonino, KP Lillerud… - Chemical Society …, 2010 - pubs.rsc.org
The large unit cells, the enormous flexibility and variation in structural motifs of MOFs
represent a big challenge in the characterization of MOF materials, particularly in cases …

Operando Time-Resolved X-ray Absorption Fine Structure Study for Surface Events on a Pt3Co/C Cathode Catalyst in a Polymer Electrolyte Fuel Cell during Voltage …

N Ishiguro, T Saida, T Uruga, S Nagamatsu… - Acs …, 2012 - ACS Publications
The structural kinetics of surface events on a Pt3Co/C cathode catalyst in a polymer
electrolyte fuel cell (PEFC) was investigated by operando time-resolved X-ray absorption …