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Halogen-mediated conversion of hydrocarbons to commodities
Halogen chemistry plays a central role in the industrial manufacture of various important
chemicals, pharmaceuticals, and polymers. It involves the reaction of halogens or halides …
chemicals, pharmaceuticals, and polymers. It involves the reaction of halogens or halides …
Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …
Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …
Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts
AI Frenkel - Chemical Society Reviews, 2012 - pubs.rsc.org
Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to study
short range order in heterometallic alloys for almost four decades. In this critical review …
short range order in heterometallic alloys for almost four decades. In this critical review …
Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach
We report a careful characterization of the interaction of NH3 with the Cu (II) sites of the
[Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known …
[Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known …
Quantitative structural determination of active sites from in situ and operando XANES spectra: From standard ab initio simulations to chemometric and machine …
In the last decade the appearance of progressively more sophisticated codes, together with
the increased computational capabilities, has made XANES a spectroscopic technique able …
the increased computational capabilities, has made XANES a spectroscopic technique able …
Multivariate curve resolution analysis applied to time-resolved synchrotron X-ray Absorption Spectroscopy monitoring of the activation of copper alumina catalyst
The pure X-ray Absorption (XAS) spectral constituents and related concentration profiles
characterizing the reduction of a copper-based catalyst supported on hierarchically porous …
characterizing the reduction of a copper-based catalyst supported on hierarchically porous …
Probing reactive platinum sites in UiO-67 zirconium metal–organic frameworks
We present three methods of the synthesis of zirconium metal–organic framework UiO-67
functionalized with platinum bipyridine coordination complexes (bpydcPtIICl2 and …
functionalized with platinum bipyridine coordination complexes (bpydcPtIICl2 and …
X-ray absorption spectroscopies: useful tools to understand metallorganic frameworks structure and reactivity
The large unit cells, the enormous flexibility and variation in structural motifs of MOFs
represent a big challenge in the characterization of MOF materials, particularly in cases …
represent a big challenge in the characterization of MOF materials, particularly in cases …
Operando Time-Resolved X-ray Absorption Fine Structure Study for Surface Events on a Pt3Co/C Cathode Catalyst in a Polymer Electrolyte Fuel Cell during Voltage …
N Ishiguro, T Saida, T Uruga, S Nagamatsu… - Acs …, 2012 - ACS Publications
The structural kinetics of surface events on a Pt3Co/C cathode catalyst in a polymer
electrolyte fuel cell (PEFC) was investigated by operando time-resolved X-ray absorption …
electrolyte fuel cell (PEFC) was investigated by operando time-resolved X-ray absorption …