Recent developments in vanadium-catalyzed olefin coordination polymerization

AMF Phillips, H Suo, C Maria de Fátima… - Coordination Chemistry …, 2020 - Elsevier
Polyolefins account for two thirds by weight of the global synthetic polymers. There are more
than 300 grades of commercial polyolefins, whose properties depend on their …

Recent developments in catalyst systems for selective oligomerization and polymerization of higher α-olefins

N Patel, V Valodkar, G Tembe - Polymer Chemistry, 2023 - pubs.rsc.org
In this study, a comprehensive review of the recent developments in the use of various types
of homogeneous and heterogeneous catalysts for the dimerization, oligomerization and …

[HTML][HTML] Developments in vanadium-catalysed polymerisation reactions: A review

H Ishikura, R Neven, T Lange, A Galetova, B Blom… - Inorganica Chimica …, 2021 - Elsevier
While several reviews have been devoted to lower (ethylene and propylene) olefin
polymerisation, several other substrates catalysed by vanadium complexes have escaped …

Synthesis of highly isotactic poly 1-hexene using Fe-doped Mg(OEt)2/TiCl4/ED Ziegler–Natta catalytic system

F Nouri-Ahangarani, N Bahri-Laleh… - Designed Monomers …, 2016 - Taylor & Francis
In this article, polymerization of 1-hexene with FeCl3-doped Mg (OET) 2/TiCl4/electron
donor (ED) catalytic system is presented. For this purpose, first a number of TiCl4 catalysts …

Preparation of ansa-metallocenes for production of poly (α-olefin) lubricants

JH Park, YE Jang, JY Jeon, MJ Go, J Lee, SK Kim… - Dalton …, 2014 - pubs.rsc.org
An ansa-zirconocene bearing methyl substituents at all positions adjacent to the bridgehead
[(–C (Ph) HC (Ph) H–)(η5-2, 5-Me2C5H2) 2ZrCl2](4) was prepared in high yields (78%) …

[HTML][HTML] Performance of Aromatic Amine-Modified Metallocene Polyalphaolefin Lubricant Base Oil

J Xu, Q Hu, J Li - Lubricants, 2024 - mdpi.com
With the continuous advancement of industrial technology, higher demands have been
placed on the properties of gear oils, such as oxidation stability and shear resistance …

Vinyl-addition copolymerization of norbornene and 1-octene catalyzed by a non-bridged half-titanocene with a tetrazole-phenoxy ligand

CG Chae, JY Ryu, LNT Ho, W Lee, DG Kim, S Park… - Polymer, 2024 - Elsevier
A catalyst system comprising Cp* TiCl 2 (OPhTz)(Cp*= C 5 Me 5, OPhTz= tetrazole-mono-
ortho-substituted phenoxy anion), i Bu 3 Al, and [Ph 3 C][B (C 6 F 5) 4] is employed in the …

Impact of Vanadium Complexes with Tetradentate Schiff Base Ligands on the DPPC and EYL Liposome Membranes: EPR Studies

D Man, B Pytel, M Białek - Applied Sciences, 2023 - mdpi.com
This paper investigates the effect of three vanadium complexes with Schiff base-type
tetradentate ligands of general formula N, N′-1, 2-cyclohexylenebis (3, 5 …

Synthesizing ethylene/1-octene copolymer and its nanocomposites with graphene and carbon nanotubes using a Ziegler− Natta catalyst

S Assar, GH Zohuri, N Ramezanian… - … Science, Part A, 2020 - Taylor & Francis
Copolymerization of ethylene and 1-octene was carried out using a Ziegler-Natta catalyst
and the optimization of copolymerization conditions was studied. The optimum …

Synthesis of metallocene catalyzed ethylene 1, 7-octadiene copolymer: effect of copolymerization on polymer properties

M Rahaman, IA Hussein, A Aldalbahi, A Parvez… - Macromolecular …, 2018 - Springer
In this article, metallocene catalyzed polyethylene homopolymer and ethylene 1, 7-
octadiene copolymers were synthesized and the produced polymers were characterized …