Pd-catalyzed cross-coupling reactions that form C–N bonds have become useful methods to
synthesize anilines and aniline derivatives, an important class of compounds throughout …

The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Localized surface plasmon resonance (LSPR) is a physical phenomenon exhibited by
nanoparticles of metals including coinage metals, alkali metals, aluminum, and some …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric
organometallic studies has enabled the elucidation of the mechanistic underpinnings to a …

Ligands, especially phosphines and carbenes, can play a key role in modifying and
controlling homogeneous organometallic catalysts, and they often provide a convenient …

Machine-learning methods have great potential to accelerate the identification of reaction
conditions for chemical transformations. A tool that gives substrate-adaptive conditions for …

Magnetic iron oxide nanoparticles (MIONPs) are an efficient retrievable catalytic system
recognized for their broad applications in numerous fields, including pharmaceutical …

Axially chiral biaryl structures are unique systems encountered in various synthetic
compounds such as BINAP and BINOL, polymers, but also in natural products presenting a …