Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

The cross-electrophile dialkylation of alkenes enables the formation of two C (sp3)–C (sp3)
bonds from readily available starting materials in a single transformation, thereby providing …

Organic electrosynthesis is a green strategy for the synthesis of valuable molecules.
Electrochemical reactions using sacrificial metal anodes enable new reactivity to be …

An organoelectrophotocatalytic approach for the C–H silylation of heteroarenes through
dehydrogenation cross-coupling with H2 evolution has been developed. The …

Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …

Compared with general redox chemistry, electrochemistry using the electron as a potent,
controllable, yet traceless alternative to chemical oxidants/reductants usually offers more …

Hydrogen-atom transfer mediated by earth-abundant transition-metal hydrides (M-Hs) has
emerged as a powerful tool in organic synthesis. Current methods to generate M-Hs most …

A visible-light-driven silyl radical generation method from silylboronates has been
developed. The activation of silylboronates with a catalytic amount of mild base promoted …

Radical-polar crossover (RPC) reaction bridges the gap between one-and two-electron
reactivities, thus providing an ideal solution to overcome the limitations of both radical and …