Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination

TR Cook, PJ Stang - Chemical reviews, 2015 - ACS Publications
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Polypyridyl Ru (II) or cyclometalated Ir (III) functionalized architectures for photocatalysis

YL Li, AJ Li, SL Huang, JJ Vittal, GY Yang - Chemical Society Reviews, 2023 - pubs.rsc.org
The chemistry of polypyridyl Ru (II) and cyclometalated Ir (III) derivatives provides long-
lasting interest to researchers due to the inherent advantage of their triplet states in a variety …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages

SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …

Strategies for binding multiple guests in metal–organic cages

FJ Rizzuto, LKS von Krbek, JR Nitschke - Nature Reviews Chemistry, 2019 - nature.com
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …

Chiral metallosupramolecular architectures

LJ Chen, HB Yang, M Shionoya - Chemical Society Reviews, 2017 - pubs.rsc.org
Over the past few decades, supramolecular chirality in discrete metallosupramolecular
architectures has received considerable attention. In this review, a comprehensive summary …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Multicomponent platinum (II) cages with tunable emission and amino acid sensing

M Zhang, ML Saha, M Wang, Z Zhou… - Journal of the …, 2017 - ACS Publications
The syntheses, characterization, and emission properties of three tetragonal prismatic
cages, 4a–4c, constructed from eight 90° Pt (II) acceptors, four linear dipyridyl ligands, and …

Coordination cages as permanently porous ionic liquids

L Ma, CJE Haynes, AB Grommet, A Walczak… - Nature Chemistry, 2020 - nature.com
Porous materials are widely used in industry for applications that include chemical
separations and gas scrubbing. These materials are typically porous solids, although the …

Chiral metal–organic cages/containers (MOCs): From structural and stereochemical design to applications

M Pan, K Wu, JH Zhang, CY Su - Coordination Chemistry Reviews, 2019 - Elsevier
During the past few decades, great efforts have been devoted to the design and self-
assembly of discrete metal–organic cages/containers (MOCs) with increasing complexity …