Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Electrocatalytic ammonia oxidation (AO) provides an attractive route to a carbon-neutral fuel
economy and the energy-efficient production of value-added feedstocks. The design and …

Molecular catalysts for ammonia oxidation to dinitrogen represent enabling components to
utilize ammonia as a fuel and/or source of hydrogen. Ammonia oxidation requires not only …

The electrochemical conversion of ammonia to dinitrogen in a direct ammonia fuel cell
(DAFC) is a necessary technology for the realization of a nitrogen economy. Previous efforts …

In the past few decades, renewable-energy-driven fuel cell technologies have been widely
investigated as promising approaches to alleviate the energy and environmental crisis …

A century after hydrazine was discovered, its synthesis remains a challenge due to its high
energy requirement and favourable subsequent conversion. As an alternative to the …

Proton-coupled electron transfer (PCET) reactions are increasingly being studied in
nonaqueous conditions, where the thermochemistry of PCET substrates is largely unknown …

Oxidation of ammonia by molecular complexes is a burgeoning area of research, with critical
scientific challenges that must be addressed. A fundamental understanding of individual …

Parent amido complexes are crucial intermediates in ammonia-based transformations. We
report a well-defined ferric ammine system [Cp* Fe (1, 2-Ph2PC6H4NH)(NH3)]+([1-NH3]+) …