Multiphase chemistry at the atmosphere–biosphere interface influencing climate and public health in the anthropocene

U Pöschl, M Shiraiwa - Chemical reviews, 2015 - ACS Publications
Multiphase chemistry plays a vital role in the Earth system, climate, and health. Chemical
reactions, mass transport, and phase transitions between gases, liquids, and solids are …

Ice nucleation by particles immersed in supercooled cloud droplets

BJ Murray, D O'sullivan, JD Atkinson… - Chemical Society …, 2012 - pubs.rsc.org
The formation of ice particles in the Earth's atmosphere strongly affects the properties of
clouds and their impact on climate. Despite the importance of ice formation in determining …

The role of organic aerosol in atmospheric ice nucleation: A review

DA Knopf, PA Alpert, B Wang - ACS Earth and Space Chemistry, 2018 - ACS Publications
Predicting the formation of ice in the atmosphere presents one of the great challenges in
physical sciences with important implications for the chemistry and composition of the …

The formation, properties and impact of secondary organic aerosol: current and emerging issues

M Hallquist, JC Wenger, U Baltensperger… - Atmospheric …, 2009 - acp.copernicus.org
Secondary organic aerosol (SOA) accounts for a significant fraction of ambient tropospheric
aerosol and a detailed knowledge of the formation, properties and transformation of SOA is …

Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere

T Koop, J Bookhold, M Shiraiwa… - Physical Chemistry …, 2011 - pubs.rsc.org
Recently, it has been proposed that organic aerosol particles in the atmosphere can exist in
an amorphous semi-solid or solid (ie glassy) state. In this perspective, we analyse and …

Gas uptake and chemical aging of semisolid organic aerosol particles

M Shiraiwa, M Ammann, T Koop, U Pöschl - Proceedings of the National …, 2011 - pnas.org
Organic substances can adopt an amorphous solid or semisolid state, influencing the rate of
heterogeneous reactions and multiphase processes in atmospheric aerosols. Here we …

An amorphous solid state of biogenic secondary organic aerosol particles

A Virtanen, J Joutsensaari, T Koop, J Kannosto… - Nature, 2010 - nature.com
Secondary organic aerosol (SOA) particles are formed in the atmosphere from condensable
oxidation products of anthropogenic and biogenic volatile organic compounds (VOCs) …

New and extended parameterization of the thermodynamic model AIOMFAC: calculation of activity coefficients for organic-inorganic mixtures containing carboxyl …

A Zuend, C Marcolli, AM Booth… - Atmospheric …, 2011 - acp.copernicus.org
We present a new and considerably extended parameterization of the thermodynamic
activity coefficient model AIOMFAC (Aerosol Inorganic-Organic Mixtures Functional groups …

Amorphous and crystalline aerosol particles interacting with water vapor: conceptual framework and experimental evidence for restructuring, phase transitions and …

E Mikhailov, S Vlasenko, ST Martin… - Atmospheric …, 2009 - acp.copernicus.org
Interactions with water are crucial for the properties, transformation and climate effects of
atmospheric aerosols. Here we present a conceptual framework for the interaction of …

Do atmospheric aerosols form glasses?

B Zobrist, C Marcolli, DA Pedernera… - … Chemistry and Physics, 2008 - acp.copernicus.org
A new process is presented by which water soluble organics might influence ice nucleation,
ice growth, chemical reactions and water uptake of aerosols in the upper troposphere: the …