Coordinative Chain Transfer and chain shuttling polymerization

R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …

Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges

G Zanchin, G Leone - Progress in Polymer Science, 2021 - Elsevier
Polyolefins have dominated materials technology over the last century and remain among
the most used materials, despite environmental problems have emerged and their public …

Polyolefins vitrimers: design principles and applications

M Ahmadi, A Hanifpour, S Ghiassinejad… - Chemistry of …, 2022 - ACS Publications
Less than 10% of plastics are recycled worldwide, among which polyolefins, which form two-
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …

Circular polyolefins: advances toward a sustainable future

D Hassanian-Moghaddam, N Asghari… - Macromolecules, 2023 - ACS Publications
Plastics offer several advantages, but their production and disposal processes have severe
environmental implications. To overcome these issues, there is a need to switch from the …

Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

W Wang, W Lu, A Goodwin, H Wang, P Yin… - Progress in polymer …, 2019 - Elsevier
Thermoplastic elastomers (TPEs) have found use in a wide range of applications, such as
adhesives, elastomers, coatings, fibers, and in additive manufacturing techniques such as …

Synthesis and characterization of polyolefin thermoplastic elastomers: A review

M Sun, Y **ao, K Liu, X Yang, P Liu… - … Canadian Journal of …, 2023 - Wiley Online Library
Polyolefin thermoplastic elastomers (TPE‐Os) are high‐performance polyolefins consisting
of both plastic and rubber phases. Compared with other thermoplastic elastomers, the TPE …

Development of well-defined olefin block (co) polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization

Y Wang, J Lai, Q Gou, R Gao, G Zheng, R Zhang… - Coordination Chemistry …, 2025 - Elsevier
As the saturation rate of the bulk polyolefin market accelerates, the development of high
value-added polyolefins becomes increasingly urgent. Particular attention is directed …

Chain-straightening polymerization of olefins to form polar functionalized semicrystalline polyethylene

JM Eagan, O Padilla-Vélez, KS O'Connor… - …, 2022 - ACS Publications
We report the design and synthesis of an α-diimine PdII catalyst that copolymerizes
functionalized and long chain α-olefins to produce semicrystalline polyethylene materials …

A comprehensive picture on chain walking olefin polymerization

Y Zhang, Y Zhang, Z Jian - Polymer, 2023 - Elsevier
Abstract α-Diimine nickel and palladium catalyzed α-olefin polymerization could produce
polyolefins with complicated branching structures due to the chain walking feature. The …

Cyclic olefin copolymers containing both linear polyethylene and poly (ethylene-co-norbornene) segments prepared from chain shuttling copolymerization of ethylene …

H Gao, S Chen, B Du, Z Dai, X Lu, K Zhang, L Pan… - Polymer …, 2022 - pubs.rsc.org
Semicrystalline polyethylene (PE) and amorphous poly (ethylene-co-norbornene)
copolymers have been used in a wide variety of applications, especially in packaging. It is a …