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Coordinative Chain Transfer and chain shuttling polymerization
R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …
polymerization process that has a wide range of applications. It allows a highly controlled …
Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges
Polyolefins have dominated materials technology over the last century and remain among
the most used materials, despite environmental problems have emerged and their public …
the most used materials, despite environmental problems have emerged and their public …
Polyolefins vitrimers: design principles and applications
Less than 10% of plastics are recycled worldwide, among which polyolefins, which form two-
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …
Circular polyolefins: advances toward a sustainable future
D Hassanian-Moghaddam, N Asghari… - Macromolecules, 2023 - ACS Publications
Plastics offer several advantages, but their production and disposal processes have severe
environmental implications. To overcome these issues, there is a need to switch from the …
environmental implications. To overcome these issues, there is a need to switch from the …
Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry
Thermoplastic elastomers (TPEs) have found use in a wide range of applications, such as
adhesives, elastomers, coatings, fibers, and in additive manufacturing techniques such as …
adhesives, elastomers, coatings, fibers, and in additive manufacturing techniques such as …
Synthesis and characterization of polyolefin thermoplastic elastomers: A review
Polyolefin thermoplastic elastomers (TPE‐Os) are high‐performance polyolefins consisting
of both plastic and rubber phases. Compared with other thermoplastic elastomers, the TPE …
of both plastic and rubber phases. Compared with other thermoplastic elastomers, the TPE …
Development of well-defined olefin block (co) polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization
Y Wang, J Lai, Q Gou, R Gao, G Zheng, R Zhang… - Coordination Chemistry …, 2025 - Elsevier
As the saturation rate of the bulk polyolefin market accelerates, the development of high
value-added polyolefins becomes increasingly urgent. Particular attention is directed …
value-added polyolefins becomes increasingly urgent. Particular attention is directed …
Chain-straightening polymerization of olefins to form polar functionalized semicrystalline polyethylene
JM Eagan, O Padilla-Vélez, KS O'Connor… - …, 2022 - ACS Publications
We report the design and synthesis of an α-diimine PdII catalyst that copolymerizes
functionalized and long chain α-olefins to produce semicrystalline polyethylene materials …
functionalized and long chain α-olefins to produce semicrystalline polyethylene materials …
A comprehensive picture on chain walking olefin polymerization
Y Zhang, Y Zhang, Z Jian - Polymer, 2023 - Elsevier
Abstract α-Diimine nickel and palladium catalyzed α-olefin polymerization could produce
polyolefins with complicated branching structures due to the chain walking feature. The …
polyolefins with complicated branching structures due to the chain walking feature. The …
Cyclic olefin copolymers containing both linear polyethylene and poly (ethylene-co-norbornene) segments prepared from chain shuttling copolymerization of ethylene …
H Gao, S Chen, B Du, Z Dai, X Lu, K Zhang, L Pan… - Polymer …, 2022 - pubs.rsc.org
Semicrystalline polyethylene (PE) and amorphous poly (ethylene-co-norbornene)
copolymers have been used in a wide variety of applications, especially in packaging. It is a …
copolymers have been used in a wide variety of applications, especially in packaging. It is a …