The organometallic chemistry of the rare-earth metals (the term “rare-earth metal” in this
article will include scandium and yttrium alongside the elements from lanthanum to lutetium …

Magnetic lanthanide–transition-metal hybrid materials have enjoyed increasing attraction
because they not only provide examples for studying magnetic coupling involving …

Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides
have become a steadily growing field in organometallic chemistry. The predominant part of …

804 WJ EVANS how the chemistry of the lanthanides was viewed during the time in which
organometallic chemistry was being developed. The early studies on organolanthanide …

The highly reactive, six-coordinate tris-aryloxide U (III) species,[((t-BuArO) 3tacn) U](1) reacts
with CO2 in a 2e-reduction to produce CO and a dinuclear U (IV/IV) μ-oxygen bridged …

New lanthanide− transition-metal (Ln− M) compounds were prepared and the structural
relationships of the metal combinations were discerned. Numerous compounds derived from …

Publisher Summary This chapter discusses organolanthanide chemistry. Organolanthanide
chemistry currently is one of the most rapidly develo** areas of organometallic chemistry …

Three new 3d− 4f heterometallic coordination polymers,[Ln2 (H2O) 4M2 (H2O) 2 (QA) 5]⊙ n
H2O (H2QA= quinolinic acid; Ln= Gd, M= Ni, n= 7 (1); Ln= Gd, M= Co, n= 6.5 (2); Ln= Dy, M …

By control of mixed ligands with particular coordination sites, three novel three-dimensional
(3D) 4d− 4f heterometallic coordination polymers,[Ln4 (H2O) 2Ag (1, 3-bdc) 4 (inic) 5]⊙ n …

Crystal engineering provides a powerful tool for the design and construction of coordination
frameworks with unique structural motifs and tunable physical properties.[1, 2] Many …