Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomically precise alloy nanoclusters

T Kawawaki, Y Imai, D Suzuki, S Kato… - … A European Journal, 2020 - Wiley Online Library
Metal nanoclusters (NCs) have a particle size of about one nanometer, which makes them
the smallest unit that can give a function to a substance. In addition, metal NCs possess …

An all-metal fullerene: [K@Au12Sb20]5−

YH Xu, WJ Tian, A Muñoz-Castro, G Frenking, ZM Sun - Science, 2023 - science.org
The C60 fullerene molecule has attracted tremendous interest for its distinctive nearly
spherical structure. By contrast, all-metal counterparts have been elusive: Fullerene-like …

Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5] catenanes built from cyclo [18] carbon

N Fedik, M Kulichenko, D Steglenko… - Chemical …, 2020 - pubs.rsc.org
The unusual stability of cyclo [18] carbon arising from its aromaticity might be used to
provide the kinetic trap** needed in the design of interlocked systems. The kinetic barrier …

Double aromaticity in a BBe 6 H 6+ cluster with a planar hexacoordinate boron structure

AJ Kalita, SS Rohman, C Kashyap, SS Ullah… - Chemical …, 2020 - pubs.rsc.org
Aromaticity is one of the central concepts in chemistry and stabilizes many clusters that have
interesting structural motifs. Herein, a cationic BBe6H6 cluster featuring a planar …

Theoretical investigation of the stability of A55-nBn nanoalloys (A, B= Al, Cu, Zn, Ag)

LR da Silva, FO Morais, JPA de Mendonça… - Computational Materials …, 2022 - Elsevier
Nanoalloys have been investigated for a wide range of applications, however, our atomistic
understanding of the physical-chemistry properties is still far from complete as quantum-size …

Tri- and Tetra-superatomic Molecules in Ligand-Protected Face-Fused Icosahedral (M@Au12)n (M = Au, Pt, Ir, and Os, and n = 3 and 4) Clusters

C Xu, Y Zhou, J Yi, D Li, L Shi… - The Journal of Physical …, 2022 - ACS Publications
Cluster assembling has been one of the hottest topics in nanochemistry. In certain ligand-
protected gold clusters, bi-icosahedral cores assembled from Au13 superatoms were found …

σ-Aromaticity in the MoS2 Monolayer

M Kulichenko, AI Boldyrev - The Journal of Physical Chemistry C, 2020 - ACS Publications
Molybdenum disulfide is a prominent semiconductor that received a lot of attention recently
due to its unique properties. Possessing a layered crystal structure, one can tune the band …

Expansion of magnetic aromaticity criteria to multilayer structures: magnetic response and spherical aromaticity of matryoshka‐like cluster [Sn@ Cu12@ Sn20] 12−

M Kulichenko, N Fedik, A Boldyrev… - … –A European Journal, 2020 - Wiley Online Library
Structural characterization of the discrete [Sn@ Cu12@ Sn20] 12− cluster exposed a
fascinating architecture composed of three concentric structural layers in which an …

Charge Transfer Surface-Enhanced Raman and Absorption Spectra of the Zwitterionic Form of Cysteine Adsorbed on M@Au12 (M = Au, Ag, Pt, and Pd) Nanoclusters

M Gerami, H Farrokhpour, N Orangi - The Journal of Physical …, 2023 - ACS Publications
The effect of the core atom type of the M@ Au12 nanocluster (M= Au, Ag, Pt, and Pd) on the
normal (NR) and charge-transfer surface-enhanced Raman spectroscopy (CT-SERS) of the …