Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y **, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Post-polymerization modification reactions of poly (glycidyl methacrylate) s

EM Muzammil, A Khan, MC Stuparu - RSC advances, 2017 - pubs.rsc.org
Post-polymerisation modification of poly (glycidyl methacrylate)(PGMA) through the
nucleophilic ring opening reactions of the pendent epoxide groups allows for the installation …

Segregation-induced in situ hydrophilic modification of poly (vinylidene fluoride) ultrafiltration membranes via sticky poly (ethylene glycol) blending

H Sun, X Yang, Y Zhang, X Cheng, Y Xu, Y Bai… - Journal of Membrane …, 2018 - Elsevier
A novel mussel-inspired sticky catechol-functionalized poly (ethylene glycol)(Cate-PEG) was
synthesized and deployed as an additive to modify the hydrophobic poly (vinylidene …

“Click”-inspired chemistry in macromolecular science: matching recent progress and user expectations

P Espeel, FE Du Prez - Macromolecules, 2015 - ACS Publications
This year, it has been a decade that the concept of “click” chemistry was pioneered in
polymer and material science by the exploration of the synthetic scope of copper-catalyzed …

Dual ionic cross-linked double network hydrogel with self-healing, conductive, and force sensitive properties

S Liu, O Oderinde, I Hussain, F Yao, G Fu - Polymer, 2018 - Elsevier
Conventional chemically cross-linked double network hydrogels (DN hydrogels) are
considered as one of the toughest soft materials. However, they lack self-healing properties …

Thiol‐epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers

MC Stuparu, A Khan - Journal of Polymer Science Part A …, 2016 - Wiley Online Library
Base‐catalyzed reaction between a thiol and an epoxide group is a simple fusion process
that leads to the formation of a β‐hydroxythio‐ether linkage. This reaction is efficient, regio …

One-pot synthesis of polyamides with various functional side groups via Passerini reaction

YZ Wang, XX Deng, L Li, ZL Li, FS Du, ZC Li - Polymer Chemistry, 2013 - pubs.rsc.org
Polyamides with various functional side groups were synthesized via Passerini reaction in a
one-pot approach. The polymerization conditions and kinetics as well as the resulting …

Facile construction of pH-and redox-responsive micelles from a biodegradable poly (β-hydroxyl amine) for drug delivery

D Li, Y Bu, L Zhang, X Wang, Y Yang… - …, 2016 - ACS Publications
Here we demonstrate a type of pH and reduction dual-sensitive biodegradable micelles,
which were self-assembled by a cationic polymer in an aqueous solution. Due to tumor cells …

Homopolymer bifunctionalization through sequential thiol–epoxy and esterification reactions: an optimization, quantification, and structural elucidation study

I Gadwal, MC Stuparu, A Khan - Polymer Chemistry, 2015 - pubs.rsc.org
In this study, we probe various aspects of a post-polymerization double-modification strategy
involving sequential thiol–epoxy and esterification reactions for the preparation of dual …

High performance graded rainbow holograms via two-stage sequential orthogonal thiol–click chemistry

H Peng, DP Nair, BA Kowalski, W **, T Gong… - …, 2014 - ACS Publications
Orthogonal, sequential “click” reactions were implemented to yield novel polymeric
substrates with the ability to record holographic data. The base-catalyzed thiol–acrylate …