Organolithium compounds have been at the forefront of synthetic chemistry for over a
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …

Organolithiumverbindungen stehen seit mehr als einem Jahrhundert an der Spitze der
Synthesechemie, da sie die Synthese von einer Vielzahl von Verbindungen ermöglichen …

Herein, a facile method is developed for the synthesis of vicinal bisphosphine derivatives
based on a cascade of hydrophosphinylation, elimination, and hydrophosphinylation of …

A lanthanide silylamide-catalyzed tandem reaction of isatins, diethyl phosphite, and 2, 3-
diarylcyclopropenones has been developed. A series of pyrano [2, 3-b] indol-2-ones were …

Advancing the applications of s‐block heterobimetallic complexes in catalysis, we report the
use of potassium magnesiate (PMDETA) 2K2Mg (CH2SiMe3) 4 [PMDETA= N, N, N', N', N'' …

The alkaline‐earth metals Mg and Ca are too inert for the direct metalation of primary and
secondary amines. Consequently, activation prior to use is required. Alternatively, the …

Metalation of dimesitylphosphane oxide, Mes2P (O) H (1), with alkali metal reagents (nBuLi,
NaH, and A (hmds); A= K, Rb, and Cs) in THF yields the corresponding …

P (O)–H compounds like H-phosphites, H-phosphinates, and H-phosphine oxides are
widely used as nucleophiles. Herein, their reactions with unsaturated compounds, C–H …

The synthesis of ethane-1, 2-diyl-bis (diarylphosphane oxides) and-phosphanes, containing
bulky ortho-substituted P-bound aryl groups, poses severe challenges, such as drastic …

The reactions of dimesitylphosphane oxide Mes2P (O) H with Lawessons reagent and
dimesitylphoshane with selenium yield Mes2P (E) H with E= S (1a) and E= Se (1b) …