Recent strategies to develop innovative photosensitizers for enhanced photodynamic therapy

TC Pham, VN Nguyen, Y Choi, S Lee, J Yoon - Chemical reviews, 2021 - ACS Publications
This review presents a robust strategy to design photosensitizers (PSs) for various species.
Photodynamic therapy (PDT) is a photochemical-based treatment approach that involves the …

Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …

W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …

Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Synthesis of corroles and their heteroanalogs

R Orłowski, D Gryko, DT Gryko - Chemical Reviews, 2017 - ACS Publications
Corroles have come a long way from being a curiosity to being a mainstream research topic.
They are now regularly synthesized in numerous research laboratories worldwide with …

Structure effects of metal corroles on energy-related small molecule activation reactions

H Lei, X Li, J Meng, H Zheng, W Zhang, R Cao - ACS Catalysis, 2019 - ACS Publications
The increasing global energy and environmental crises make it urgent to find and use
renewable, clean, and environmentally benign new energy resources. New energy …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Conformational control of cofactors in nature–the influence of protein-induced macrocycle distortion on the biological function of tetrapyrroles

MO Senge, SA MacGowan, JM O'Brien - Chemical Communications, 2015 - pubs.rsc.org
Tetrapyrrole-containing proteins are one of the most fundamental classes of enzymes in
nature and it remains an open question to give a chemical rationale for the multitude of …

Electrochemistry of corroles in nonaqueous media

Y Fang, Z Ou, KM Kadish - Chemical Reviews, 2017 - ACS Publications
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …

Homolytic versus heterolytic hydrogen evolution reaction steered by a steric effect

X Guo, N Wang, X Li, Z Zhang, J Zhao… - Angewandte Chemie …, 2020 - Wiley Online Library
Several H− H bond forming pathways have been proposed for the hydrogen evolution
reaction (HER). Revealing these HER mechanisms is of fundamental importance for the …

Reactivity and mechanism studies of hydrogen evolution catalyzed by copper corroles

H Lei, H Fang, Y Han, W Lai, X Fu, R Cao - ACS Catalysis, 2015 - ACS Publications
Several copper corrole complexes were synthesized, and their catalytic activities for
hydrogen (H2) evolution were examined. Our results showed that substituents at the meso …