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Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …
Evaporation-induced self-assembly of metal oxide inverse opals: from synthesis to applications
Conspectus Inverse opals (IOs) are highly interconnected three-dimensional macroporous
structures with applications in a variety of disciplines from optics to catalysis. For instance …
structures with applications in a variety of disciplines from optics to catalysis. For instance …
Deconvoluting the individual effects of nanoparticle proximity and size in thermocatalysis
Nanoparticle (NP) size and proximity are two physical descriptors applicable to practically all
NP-supported catalysts. However, with conventional catalyst design, independent variation …
NP-supported catalysts. However, with conventional catalyst design, independent variation …
Entropic control of HD exchange rates over dilute Pd-in-Au alloy nanoparticle catalysts
Dilute Pd-in-Au alloy catalysts are promising materials for selective hydrogenation catalysis.
Extensive surface science studies have contributed mechanistic insight on the energetic …
Extensive surface science studies have contributed mechanistic insight on the energetic …
Controlling nanoparticle placement in Au/TiO 2 inverse opal photocatalysts
Gold nanoparticle-loaded titania (Au/TiO2) inverse opals are highly ordered three-
dimensional photonic structures with enhanced photocatalytic properties. However, fine …
dimensional photonic structures with enhanced photocatalytic properties. However, fine …
Colloidal templating in catalyst design for thermocatalysis
Conventional catalyst preparative methods commonly entail the impregnation, precipitation,
and/or immobilization of nanoparticles on their supports. While convenient, such methods do …
and/or immobilization of nanoparticles on their supports. While convenient, such methods do …
Identifying the optimal Pd ensemble size in dilute PdAu alloy nanomaterials for benzaldehyde hydrogenation
Unraveling metal nuclearity effects is central for active site identification and the
development of high-performance heterogeneous catalysts. Herein, a platform of …
development of high-performance heterogeneous catalysts. Herein, a platform of …
Selective oxidation of linear alcohols: the promotional effect of water and inhibiting effect of carboxylates over dilute PdAu catalysts
JD Lee, A Filie, L Wilson, K Nguyen… - Journal of Materials …, 2024 - pubs.rsc.org
Dilute PdAu alloys are promising catalysts for selective oxidation with high activity and high
selectivity. The promotional effect of Pd for selective alcohol oxidation is strongly dependent …
selectivity. The promotional effect of Pd for selective alcohol oxidation is strongly dependent …
Dilute Pd-in-Au alloy RCT-SiO2 catalysts for enhanced oxidative methanol coupling
Dilute alloy catalysts have the potential to enhance selectivity and activity for large-scale
reactions. Highly dilute Pd-in-Au nanoparticle alloys partially embedded in porous silica …
reactions. Highly dilute Pd-in-Au nanoparticle alloys partially embedded in porous silica …
Influence of Pd Concentration in Au–Pd Nanoparticles for the Hydrogenation of Alkynes
Supported Au–Pd nanoparticles with low Pd content (between 2% and 25%) are excellent
catalysts for the selective hydrogenation of alkynes into alkenes, a crucial step for …
catalysts for the selective hydrogenation of alkynes into alkenes, a crucial step for …