The indole ring system is present in many natural products, pharmaceuticals,
agrochemicals, and other compounds of importance. 1–8 The indole unit forms the basis for …

C4-decorated indoles feature in a plethora of bioactive and functional compounds of
importance to natural product synthesis, material sciences, as well as crop protection and …

We have developed a nickel-catalyzed cross coupling of benzylic ammonium triflates with
aryl boronic acids to afford diarylmethanes and diarylethanes. This reaction proceeds under …

The rhodium catalysed conjugate addition of organometallics to activated alkenes is a
powerful synthetic tool for establishing new carbon–carbon bonds often with high …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

The cross-electrophile reaction is a promising strategy for C–C bond formation. Recent
studies have focused mainly on reactions with organic halides. Here we report a coupling …

Abstract Transition‐metal‐catalyzed Suzuki–Miyaura coupling has significantly advanced
C− C bond formation and has been well recognized in organic synthesis, pharmaceuticals …

Quaternary ammonium salts are readily prepared and show good reactivity in various
organic transformations via C–N bond cleavage. In this review we summarize reactions of …

Elimination of suitable leaving groups from 3-substituted indoles under basic or acidic
conditions readily provides alkylideneindolenine intermediates that may react with a large …

An efficient palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium
salts with aryl bromides was developed. The reactions proceeded smoothly in the presence …