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The state of the art in azaborine chemistry: new synthetic methods and applications
ZX Giustra, SY Liu - Journal of the American Chemical Society, 2018 - ACS Publications
Boron–nitrogen heteroarenes hold great promise for practical application in many areas of
chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation …
chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation …
Recent developments in azaborinine chemistry
Recent years have witnessed rapid advances in the field of BN/CC isosterism, particularly in
the case of azaborinines. Examples of each isomer have now been synthesized and …
the case of azaborinines. Examples of each isomer have now been synthesized and …
The Dewar Isomer of 1, 2‐Dihydro‐1, 2‐azaborinines: Isolation, Fragmentation, and Energy Storage
K Edel, X Yang, JSA Ishibashi… - Angewandte Chemie …, 2018 - Wiley Online Library
Abstract The photochemistry of 1, 2‐dihydro‐1, 2‐azaborinine derivatives was studied under
matrix isolation conditions and in solution. Photoisomerization occurs exclusively to the …
matrix isolation conditions and in solution. Photoisomerization occurs exclusively to the …
Scope of the Thermal Ring‐Expansion Reaction of Boroles with Organoazides
H Braunschweig, MA Celik… - … A European Journal, 2017 - Wiley Online Library
Electronic and steric factors have been investigated in the thermal ring expansion of boroles
with organic azides, a reaction that provides access to highly arylated 1, 2‐azaborinines, BN …
with organic azides, a reaction that provides access to highly arylated 1, 2‐azaborinines, BN …
Accessing 1, 2‐Substituted Cyclobutanes through 1, 2‐Azaborine Photoisomerization
ZX Giustra, X Yang, M Chen… - Angewandte Chemie …, 2019 - Wiley Online Library
We provide a seminal example of the utility of the 1, 2‐azaborine motif as a 4C+ 1N+ 1B
synthon in organic synthesis. Specifically, conditions for the practically scalable …
synthon in organic synthesis. Specifically, conditions for the practically scalable …
Intra-and inter-self-assembly of identical supramolecules on silver surfaces
Self-assembly of identical organometallic supramolecules into ordered superstructures is of
great interest in both chemical science and nanotechnology due to its potential to generate …
great interest in both chemical science and nanotechnology due to its potential to generate …
Halogen-adatom mediated phase transition of two-dimensional molecular self-assembly on a metal surface
Construction of tunable and robust two-dimensional (2D) molecular arrays with desirable
lattices and functionalities over a macroscopic scale relies on spontaneous and reversible …
lattices and functionalities over a macroscopic scale relies on spontaneous and reversible …
Transforming benzylideneamine N, C-chelate boron compounds to BN-cycloocta-/cyclohepta-trienes bearing a tetrasubstituted B [double bond, length as m-dash] N …
A series of benzylideneamine N, C-chelate boron compounds have been found to undergo
rapid multistructural transformations with UV irradiation, yielding new BN-cycloocta-1, 3, 6 …
rapid multistructural transformations with UV irradiation, yielding new BN-cycloocta-1, 3, 6 …
The computational design of two-dimensional materials
DP Miller, A Phillips, H Ludowieg… - Journal of Chemical …, 2019 - ACS Publications
A computational laboratory experiment investigating molecular models for hexagonal boron–
carbon–nitrogen sheets (h-BCN) was developed and employed in an upper-level …
carbon–nitrogen sheets (h-BCN) was developed and employed in an upper-level …
Stable π Radical BDPA: Adsorption on Cu (100) and Survival of Spin
The adsorption of the radical α, ɣ‐bisdiphenylene‐β‐phenylallyl (BDPA) molecule to the Cu
(100) surface was studied using scanning tunnelling microscopy (STM), scanning tunnelling …
(100) surface was studied using scanning tunnelling microscopy (STM), scanning tunnelling …