The state of the art in azaborine chemistry: new synthetic methods and applications

ZX Giustra, SY Liu - Journal of the American Chemical Society, 2018 - ACS Publications
Boron–nitrogen heteroarenes hold great promise for practical application in many areas of
chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation …

Recent developments in azaborinine chemistry

G Bélanger‐Chabot, H Braunschweig… - European Journal of …, 2017 - Wiley Online Library
Recent years have witnessed rapid advances in the field of BN/CC isosterism, particularly in
the case of azaborinines. Examples of each isomer have now been synthesized and …

The Dewar Isomer of 1, 2‐Dihydro‐1, 2‐azaborinines: Isolation, Fragmentation, and Energy Storage

K Edel, X Yang, JSA Ishibashi… - Angewandte Chemie …, 2018 - Wiley Online Library
Abstract The photochemistry of 1, 2‐dihydro‐1, 2‐azaborinine derivatives was studied under
matrix isolation conditions and in solution. Photoisomerization occurs exclusively to the …

Scope of the Thermal Ring‐Expansion Reaction of Boroles with Organoazides

H Braunschweig, MA Celik… - … A European Journal, 2017 - Wiley Online Library
Electronic and steric factors have been investigated in the thermal ring expansion of boroles
with organic azides, a reaction that provides access to highly arylated 1, 2‐azaborinines, BN …

Accessing 1, 2‐Substituted Cyclobutanes through 1, 2‐Azaborine Photoisomerization

ZX Giustra, X Yang, M Chen… - Angewandte Chemie …, 2019 - Wiley Online Library
We provide a seminal example of the utility of the 1, 2‐azaborine motif as a 4C+ 1N+ 1B
synthon in organic synthesis. Specifically, conditions for the practically scalable …

Intra-and inter-self-assembly of identical supramolecules on silver surfaces

L Song, B Yang, X Fan, Y Mao, H Shan… - The Journal of …, 2022 - ACS Publications
Self-assembly of identical organometallic supramolecules into ordered superstructures is of
great interest in both chemical science and nanotechnology due to its potential to generate …

Halogen-adatom mediated phase transition of two-dimensional molecular self-assembly on a metal surface

T Niu, J Wu, F Ling, S **, G Lu, M Zhou - Langmuir, 2018 - ACS Publications
Construction of tunable and robust two-dimensional (2D) molecular arrays with desirable
lattices and functionalities over a macroscopic scale relies on spontaneous and reversible …

Transforming benzylideneamine N, C-chelate boron compounds to BN-cycloocta-/cyclohepta-trienes bearing a tetrasubstituted B [double bond, length as m-dash] N …

HJ Li, SK Mellerup, X Wang, S Wang - Chemical Communications, 2018 - pubs.rsc.org
A series of benzylideneamine N, C-chelate boron compounds have been found to undergo
rapid multistructural transformations with UV irradiation, yielding new BN-cycloocta-1, 3, 6 …

The computational design of two-dimensional materials

DP Miller, A Phillips, H Ludowieg… - Journal of Chemical …, 2019 - ACS Publications
A computational laboratory experiment investigating molecular models for hexagonal boron–
carbon–nitrogen sheets (h-BCN) was developed and employed in an upper-level …

Stable π Radical BDPA: Adsorption on Cu (100) and Survival of Spin

JD Teeter, DP Miller, S Müllegger - ChemPhysChem, 2025 - Wiley Online Library
The adsorption of the radical α, ɣ‐bisdiphenylene‐β‐phenylallyl (BDPA) molecule to the Cu
(100) surface was studied using scanning tunnelling microscopy (STM), scanning tunnelling …