The carbon–carbon (C–C) bond cleavage of cyclopropanols is a wide area of research with
much current activity. This review highlights new developments in this area over the past two …

In recent years, transition‐metal‐catalyzed C− H activation has become a key strategy in the
field of organic synthesis. Rhodium complexes are widely used as catalysts in a variety of …

The indole scaffold will continue to play a vital part in the future of drug discovery and
agrochemical development. Because of this, the necessity for elegant techniques to enable …

C7-Decorated indoles are important structural motifs present in a plethora of bioactive and
pharmaceutical compounds. Early stage developments for C7 modifications were realized …

Metal-catalysed functionalization of a carbon–hydrogen bond can occur selectively even in
the presence of ostensibly more reactive functional groups. Such conversions have changed …

Selective editing of the benzenoid C− H bonds (C4− C7) in indoles/indolines has received
great interest because functionalized indoles/indolines are featured in many marketed drugs …

The merging of C–H and C–C bond cleavage into one single chemical process remains a
daunting challenge, especially in an asymmetric manner. Herein, a Pd (II)-catalyzed …

Until now, the selective (hetero) aryl C–H alkylation without the assistance of directing
groups or preinstallation of functionalities still remains a highly challenging goal. Herein, by …

Homoenolates are unique synthetic intermediates which display umpolung reactivity.
Homoenolates and homoenolate equivalents like cyclopropanols have seen a recent surge …

The Rh (III)-catalyzed C–H oxidative alkylation of aniline derivatives with readily available
secondary allyl alcohols using a pyrimidine-directing group, leading to the production of β …