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From terpenes to sustainable and functional polymers
Our dependence on fossil-fuel based raw materials and alarming plastics accumulation in
the environment has inspired many scientists to design and implement more sustainable …
the environment has inspired many scientists to design and implement more sustainable …
Crafting sustainable solutions: architecting biodegradable copolymers through controlled ring-opening copolymerization
Polylactic acid (PLA) is a biodegradable and biocompatible polymer with versatile
applications in packaging and medicine. It is derived from lactic acid and thus represents an …
applications in packaging and medicine. It is derived from lactic acid and thus represents an …
[HTML][HTML] Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2 with Epoxides
V Paradiso, V Capaccio, DH Lamparelli… - Catalysts, 2020 - mdpi.com
Coupling of CO2 with epoxides is a green emerging alternative for the synthesis of cyclic
organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to …
organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to …
Cooperative heterometallic catalysts: balancing activity and control in PCL-block-PLA copolymer synthesis
MA Rahman, TJ Neal, JA Garden - Chemical Communications, 2024 - pubs.rsc.org
Heterometallic cooperativity is gaining momentum in cyclic ester ring-opening
polymerisation, yet remains surprisingly underexplored in their block copolymerisations …
polymerisation, yet remains surprisingly underexplored in their block copolymerisations …
Stereoselective polymerization of biosourced terpenes β-myrcene and β-ocimene and their copolymerization with styrene promoted by titanium catalysts
The stereoselective polymerization of β-myrcene and β-ocimene and their binary
copolymerization with styrene promoted by titanium complexes dichloro {1, 4 …
copolymerization with styrene promoted by titanium complexes dichloro {1, 4 …
Use of titanocalix [4] arenes in the ring opening polymerization of cyclic esters
Z Sun, Y Zhao, O Santoro, MRJ Elsegood… - Catalysis Science & …, 2020 - pubs.rsc.org
The known dichloride complexes [TiCl2L (O) 2 (OR) 2](type I: R= Me (1), n-Pr (2) and n-
pentyl (3); L (OH) 2 (OR) 2= 1, 3-dialkyloxy-p-tert-butylcalix [4] arene), together with the new …
pentyl (3); L (OH) 2 (OR) 2= 1, 3-dialkyloxy-p-tert-butylcalix [4] arene), together with the new …
[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis
V Paradiso, V Capaccio, DH Lamparelli… - Coordination Chemistry …, 2021 - Elsevier
Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes
bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches …
bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches …
Highly efficient and well-controlled ROP and copolymerization of cyclic esters using a cesium complex
A cesium imino-phosphanamidinate,[{NHIDippP (Ph) NDipp} Cs], enabling efficient ring-
opening (co) polymerization of rac-LA and ε-CL is disclosed. Owing to the highly controlled …
opening (co) polymerization of rac-LA and ε-CL is disclosed. Owing to the highly controlled …
Ring-Opening Polymerization (ROP) of cyclic esters by a versatile aluminum Diphenoxyimine Complex: From polylactide to random copolymers
FM Garcia-Valle, T Cuenca, MEG Mosquera… - European polymer …, 2020 - Elsevier
Abstract Aluminum complex [AlMeL 2](1),(L= N-(2, 6-diisopropylphenyl)-phenoxyimine),
promotes the Ring-Opening Polymerization (ROP) of L-and rac-lactide, and the …
promotes the Ring-Opening Polymerization (ROP) of L-and rac-lactide, and the …
Titanium pyridonates for the homo-and copolymerization of rac-lactide and ε-caprolactone
A series of titanium pyridonate complexes have been synthesized under very mild reaction
conditions from a common precursor, Ti (NMe2) 4. These complexes have been explored as …
conditions from a common precursor, Ti (NMe2) 4. These complexes have been explored as …